固态粒子因子对浮动法处理的油性泥石油固态分离的影响和机制
Shuhui Wu1, Xue Yao1, Xiao Wang1
1School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China.
Toxics
|January 8, 2025
概括
研究油性污泥 (OS) 颗粒大小对油固体分离的影响,发现较粗的颗粒提高了效率. 确定了最佳漂浮条件,将残留油含量降低到混合尺寸OS的2.63%.
科学领域:
- 环境工程 环境工程
- 分离科学 分离科学
- 材料科学 材料科学 材料科学
背景情况:
- 固体相组成显著影响油性污泥 (OS) 油固体分离效率.
- 了解颗粒大小的影响对于优化OS处理至关重要.
研究的目的:
- 研究固态粒子因子对OS残留阶段的油含量的影响和机制.
- 通过颗粒大小操纵和漂浮参数优化,提高油固体分离效率.
主要方法:
- 漂浮实验是在没有漂浮试剂的单尺寸和混合尺寸沙子操作系统上进行的.
- 研究的粒子大小,漂浮温度 (Tp),漂浮时间 (Tt),叶轮转速 (Rs) 和液体/固体比率 (L/OS) 的影响.
- 利用扫描电子显微镜 (SEM),富里埃变换红外光谱 (FT-IR),经典第一阶模型和响应表面方法 (RSM).
主要成果:
- 在残基阶段的油含量随着固体阶段颗粒大小的增加而减少,对于单一大小的沙子OS.
- 确定了最佳漂浮条件:Tp 50 °C,Tt 25 分钟,Rs 1450 r/min,L/OS 12:1.
- 混合尺寸的沙子OS显示出更明显的油固体分离,使用RSM优化剩余油含量为2.63%,确定RS为主要控制因素.
结论:
- 粗粒子OS在油固体分离过程中具有优势.
- 在OS固态阶段的不同颗粒成分促进了油固态分离.
- 这项研究提供了关键的过程参数和有效的OS处理的理论基础.
相关概念视频
Colloidal precipitates
504
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
504
Centrifugation
2.1K
Centrifugation is a separation technique based on differences in density or size. It is commonly used to separate solids from aqueous interferents. During centrifugation, the sample is placed in centrifugation tubes and spun at high angular velocity, which allows centrifugal force to act differentially on the different densities or masses of the components. After spinning, the supernatant liquid is decanted. Depending on the specific application, either the pellet or the supernatant is retained...
2.1K
Optimizing Chromatographic Separations
340
Optimizing chromatographic separations is crucial for obtaining clean separations in a minimum amount of time. Optimization is required for several factors, including kinetic effects related to band broadening, plate height, capacity factor, and separation factor.
Band broadening refers to spreading solute bands as they travel through the column. This broadening can impact resolution. Plate height (H) represents the length required for one theoretical plate. A lower plate height corresponds to...
Band broadening refers to spreading solute bands as they travel through the column. This broadening can impact resolution. Plate height (H) represents the length required for one theoretical plate. A lower plate height corresponds to...
340
Coagulation
264
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
264
Colloids
17.3K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
17.3K
Extraction: Advanced Methods
409
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
409


