来自玉米皮的活性纳米纤维素:在批量废水中应用于As和Pb吸附动力学
Aydeé M Solano-Reynoso1,2,3, Ruth Fany Quispe-Quispe4, Yudith Choque-Quispe2,4
1Basic Sciences Department, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru.
Polymers
|January 8, 2025
概括
来自玉米残留的纤维素纳米晶体有效地从水中去除 (Pb) 和 (As). 这项研究利用这些新型纳米材料优化了重金属吸附的条件.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 纳米技术 纳米技术
背景情况:
- 水溶液中的重金属污染对环境和健康构成重大风险.
- 开发有效和可持续的吸附剂来去除重金属至关重要.
研究的目的:
- 从玉米残留物中合成和描述纤维素纳米晶体 (NCC).
- 评估这些NCCs在从水溶液中去除 (Pb) 和 (As) 的有效性.
主要方法:
- 玉米通过性消化,漂白和化进行加工,以产生NCCs.
- 吸附实验通过改变pH和NCC剂量进行,优化使用非线性回归.
- 使用伪一阶 (PFO) 和伪二阶 (PSO) 模型分析了吸附动力学.
主要成果:
- 鉴定证实了具有纳米尺寸,负泽塔电位,零电荷的酸点,多孔结构和高化功能组的NCC.
- 在pH值8.0和20 mg/L的NCC剂量下,可以达到最佳的去除.
- 吸附动力学遵循PFO,PSO和Elovich模型 (R2>0.974),对Pb的吸附能力高于As.
结论:
- 玉米残留物衍生的NCC显示出作为重金属去除的可持续吸附剂的巨大潜力.
- 这项研究提供了优化参数和动态见解,用于在水资源整治中使用NCC.
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