在聚氧甲中局部不弹性的温度区域
Viktor A Lomovskoy1, Svetlana A Shatokhina1, Raisa A Alekhina1
1Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS), Leninskiy Prospekt 31, 119071 Moscow, Russia.
Polymers
|January 8, 2025
概括
这项研究研究了聚氧甲共聚合物 (POM-C) 的内部摩擦,揭示了五种不同的消散过程. 化显著增加了聚合物系统中的放松微异质性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 固态物理 固态物理
背景情况:
- 像多氧甲与三 (POM-C) 这样的无形晶体共聚物体表现出复杂的机械行为.
- 了解内部摩擦和放松过程对于预测聚合物性能至关重要.
研究的目的:
- 分析POM-C的内部摩擦光谱和温度依赖的频率.
- 描述消散过程及其对回火的反应.
主要方法:
- 研究了内部摩擦和自由化的振荡频率,从-150°C到+170°C.
- 应用了标准线性固体的现象学模型,用于计算.
- 分析了消散过程的物理-机械和物理-化学特征.
主要成果:
- 在POM-C中确定了五个具有不同强度的局部消散过程.
- 观察到异常频率下降与强烈的散射损失相关.
- 在回火后,在消耗过程强度和剪模量缺陷中发现了最小的变化.
结论:
- 化显著增加了POM-C中的放松微异质性.
- 计算的激活能量和放松时间与化有很小的差异.
- 这项研究为POM-C.的粘弹性行为提供了详细的见解.
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