合成双金属合的花酸盐-胺复合物,作为高防火安全性环氧树脂的有效添加剂
Shunxiang Wang1, Jianfeng Huang1, An Wei1
1College of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China.
Polymers
|January 8, 2025
概括
一种新型的阻燃剂,双金属合甲酸胺 (BPM),显著降低了环氧树脂 (EP) 中的火灾危险. 这种材料降低了热释放和烟雾产生,提高了聚合物复合材料的安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 消防安全工程 消防安全工程
背景情况:
- 环氧树脂 (EP) 由于危险的烟雾和有毒气体释放,造成火灾风险.
- 由于EP固有的易燃性和燃烧副产品,EP的应用有限.
- 开发有效的EP阻燃剂对于提高消防安全至关重要.
研究的目的:
- 开发一种用于环氧树脂的新型阻燃剂.
- 为了研究双金属合甲酸-胺 (BPM) 结构的阻燃性能.
- 评估Zn2+和Fe2+兴奋剂对EP复合材料燃烧性能的影响.
主要方法:
- 用一种简单的基于溶液的合成方法将BPM纳入EP矩阵.
- 使用圆热量计来评估修改后的EP复合材料的燃烧性能.
- 分析重点是关键参数,包括热释放率,烟雾产量和火灾增长指数.
主要成果:
- 双金属合物酸胺 (BPM) 阻燃剂显著减少了50%的峰值热释放.
- 总热释放和总烟雾产量分别减少了31.7%和29.2%.
- 火灾增长指数显示,由于协同效应,火灾增长指数大幅减少了60%.
结论:
- 植物酸盐-胺结构的双金属兴奋剂提供了一种有效的策略,用于增强环氧树脂的阻燃性.
- 开发的BPM阻燃剂在减少燃烧危险方面表现出色.
- 这项研究为高分子复合材料的先进阻燃材料提供了宝贵的见解.
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