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Updated: Jun 3, 2025

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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Published on: July 28, 2022

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打断关联 π-σ-π 异构 实现 Z-保持不对称的 Tsuji-Trost 反应

Jiandong Liu1, Zhongkang Dong1, Wen-Bin Cao1

  • 1New Cornerstone Science Laboratory, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Journal of the American Chemical Society
|January 8, 2025
PubMed
概括

这项研究引入了一种新的方法,用于合成使用Z-retentive不对称的Tsuji-Trost反应的奇拉Z-olefins. 该策略控制异构化途径,使有价值的α-氨基酸衍生物能够有效地生产.

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