乙酸-2-{3-[1-(乙酸-氧) 乙-]-2,2-二-二-甲基-环丁-}乙酸
Dieter Schollmeyer1, Paul Jirsch1, Heiner Detert1
1University of Mainz, Department of Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.
IUCrData
|January 8, 2025
概括
一个新的化合物,C12H20O4,是从α-pinene合成的. 其独特的 cis 配置的和酸组在环旋butan环上以晶体形式进行了表征.
科学领域:
- 有机化学 有机化学
- 晶体学 晶体学是指结晶学.
背景情况:
- 阿尔法烯是一种易于获得的天然烯.
- 具有特定立体化学的循环butan衍生物对有机合成有兴趣.
研究的目的:
- 合成一种具有分子式C12H20O4.4的新型化合物.
- 阐明合成化合物的立体化学和晶体结构.
主要方法:
- 从α-pinene开始的多步合成.
- 用于结构确定的X射线晶体学.
主要成果:
- 目标化合物C12H20O4.4的成功三步合成.
- 在折叠的循环butan环上确定和酸部分的 cis 配置.
- 在平面 (202) 平行的晶体结构中观察碳酸结合的二极体层.
结论:
- 合成提供了一个新的循环butan衍生物.
- 晶体结构揭示了特定的分子间相互作用和固态包装.
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