将酸限制在四分化COF通道中,以实现超稳定和快速的无水质质子运输
Xiao Pang1,2, Benbing Shi1,2, Yawei Liu3
1Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, China (Z. Jiang.
Angewandte Chemie (International ed. in English)
|January 9, 2025
概括
研究人员开发了一种用于高温质子交换燃料电池的新膜. 这种膜有效地保留酸,改善无水质质子运输和燃料电池性能在广泛的温度范围内.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 酸 (H3PO4) 兴奋剂增强了高温质子交换膜燃料电池 (HT-PEMFC) 中无水质质子运输.
- 然而,H3PO4的漏是一个重大挑战,损害了膜的稳定性和导电性.
- 需要有效的策略来改善H3PO4在燃料电池膜中的保留.
研究的目的:
- 为HT-PEMFCs开发一种具有增强H3PO4保留力的新型膜.
- 为了研究改善无水质质子传输的机制.
- 为了评估新膜在高温下的性能.
主要方法:
- 将H3PO4纳入四元化共价有机框架膜 (QACOFMs) 的正电荷纳米通道.
- 利用强大的静电相互作用和限制效应来保持H3PO4.
- 质子运输特性和H3PO4在水化条件下保持的特征.
主要成果:
- 在H3PO4@QACOFMs中由于静电相互作用和封闭而实现了异常的H3PO4保留.
- 超快的无水质子运输由缩短的键长度 (<2.7 Å) 和相互连接的网络促进.
- 在60°C-200°C范围内观测到的高级无水质子传输,在200°C时的峰值导电率为379.7mS cm−1.
结论:
- H3PO4@QACOFMs显示出优异的H3PO4保留和增强的无水质质子导电性.
- 开发的膜显示出对高性能HT-PEMFC应用的显著前景.
- 这种方法为燃料电池膜中的H3PO4漏问题提供了可行的解决方案.
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