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Updated: Jun 3, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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取决于溶剂的C ((sp3) -CF3从中性四坐标Cu (III) 复合体中减少消除.

Yuecheng Weng1, Deng Pan1, Jian Wu1

  • 1Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032.

Chemistry (Weinheim an der Bergstrasse, Germany)
|January 9, 2025
PubMed
概括

铜 (III) 复合物经历了依赖于溶剂的C (sp3) -CF3键形成. 较少的极性溶剂促进协同反应,而极性溶剂在键形成之前涉及连接体解离,影响铜介导的三甲基化机制.

关键词:
(III) 是一个.这是一个协调一致的协议.分离,分离,分离.这是一个机制机制.减少性消除 减少性消除

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