矿山废岩中的二次矿物质的组成异质性:对水质的起源和影响
1Department of Geological Sciences & Geological Engineering, Queen's University, Kingston, ON K7L 3N6, Canada.
Journal of hazardous materials
|January 10, 2025
概括
矿山废物中的二级矿物质,如铁 (氧) 氧化物和硫酸,可以清除微量金属,改善水质. 先进的分析揭示了这些沉物如何控制金属的移动性和分布在经过气候变化的矿石中.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 矿物学是什么?矿物学是什么?
背景情况:
- 矿山废物材料含有二次矿物质,通过去除溶解污染物,显著影响水质.
- 铁 (氧) 氧化物和硫酸是全球各地在经过气候变化的矿山废物中常见的二次沉物.
研究的目的:
- 为了研究二次铁 (氧) 氧化物和硫酸在经过气候变化的矿山废物岩石中的矿物学和组成特征.
- 了解这些次要矿物质在清理和固定微量元素中的作用.
主要方法:
- 批量分析 (XRF,XRD) 用于整体组成.
- 自动化矿物学用于微量元素的提取.
- 微尺度LA-ICP-MS分析用于高分辨率的空间分布和元素映射.
- 分析因素以确定元素的关联.
主要成果:
- 微量金属 (V,Cr,Cd) 存在于二级Fe (Oxy) 氧化物和Ca-硫酸盐中,通常无法通过散装方法检测到.
- 金属 (?? 化物) 主要在粒边上缩,表明表面吸附,除了 (V) 在铁氧化物中,表明异构替代.
- 因子分析确定了二级矿物中不同的元素分组,与主要来源或封存机制相关.
结论:
- 二次矿物沉对于清理矿山废物中的微量元素至关重要.
- 补充矿物学和元素分析对于解释废岩环境中的微量元素行为至关重要.
- 了解这些过程有助于预测和管理矿山废物对水质的影响.
相关概念视频
Precipitation and Co-precipitation
1.7K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.7K
Classifying Matter by Composition
70.4K
Matter: Pure Substances and Mixtures
According to its composition, the matter can be classified into two broad categories — pure substances and mixtures.
A pure substance is a form of matter that has a constant composition throughout with uniform properties. For example, any sample of sucrose has the same composition and same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
A mixture is composed of two or...
According to its composition, the matter can be classified into two broad categories — pure substances and mixtures.
A pure substance is a form of matter that has a constant composition throughout with uniform properties. For example, any sample of sucrose has the same composition and same physical properties, such as melting point, color, and sweetness, regardless of the source from which it is isolated.
A mixture is composed of two or...
70.4K
Quality of Water
87
In concrete preparation, the quality of water is paramount as it affects the strength and durability of the concrete. Potable water is usually preferred; however, it must not have excessive sodium or potassium to prevent compromising the concrete's integrity. Water quality is typically evaluated based on impurities such as dissolved solids, chlorides, and sulfates, and its pH value is ideally between 6 and 8. Even slightly acidic natural water may be acceptable unless it contains harmful...
87
Deleterious Substances in Aggregate
141
Deleterious substances in aggregates can be detrimental to the quality and durability of concrete. These substances include organic impurities like loam, which interfere with cement hydration and are usually present in the sand. These prevent a good bond between aggregate and cement paste. Organic impurities can be detected using the colorimetric test, where the darkness of a solution after agitation indicates the level of organic content.
Another type of impurity is clay and fine material that...
Another type of impurity is clay and fine material that...
141
Factors Affecting Solubility
33.0K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.0K
Unsoundness of Aggregate due to Volume Change
96
Unsoundness in aggregates due to volume changes is primarily caused by the physical alterations aggregates undergo, such as freezing and thawing, thermal changes, and wetting and drying. Unsound aggregates, when subjected to these changes, result in volume change upon disintegration. This, in turn, contributes to the deterioration of concrete, including scaling, pop-outs, and cracking. Particular types of aggregates, such as porous flints, cherts, and those containing clay minerals, are...
96


