边界滑与吸收的阳离子表面活性剂Bilayers在硬水中的边界滑
Aya Toyoda1, Hikaru Kimura1, Tadashi Sugahara2
1R&D - Analytical Science Research, Kao Corporation, 1334 minato, Wakayama, Wakayama 640-8580, Japan.
Langmuir : the ACS journal of surfaces and colloids
|January 10, 2025
概括
基硫酸盐 (C18HAS) 在硬水中的表面形成滑双层薄膜. 这些薄膜由于在基链之间滑动而表现出极低的摩擦,而不是头组.
科学领域:
- 表面科学是一门学科.
- 部落学 (tribology) 是一个学科.
- 合体和表面化学
背景情况:
- 阳离子表面活性剂可以形成复杂的结构,如溶液中的囊泡.
- 充电表面的表面活性剂吸附受溶液化学的影响,例如硬水离子.
- 了解界面行为对于设计有效的滑剂至关重要.
研究的目的:
- 为了研究基硫酸盐 (C18HAS) 在硬水中的 mica 上的吸附.
- 为了描述由此产生的滑膜结构和特性.
- 为了阐明观察到的低摩擦背后的机制.
主要方法:
- 原子力显微镜 (AFM) 用于测量吸附的双层厚度.
- 表面力装置 (SFA) 用于评估摩擦和滑性能.
- 对C18HAS从硬水溶液中吸附到表面的研究.
主要成果:
- 在硬水中,C18HAS形成了囊泡,通过Ca2+桥接吸附到负电荷的上.
- 吸附层转化为双层薄膜,厚度随时间变化而增加.
- 封闭的C18HAS薄膜具有10-3或以下的摩擦系数 (μ).
结论:
- 较低的摩擦源于吸附双层内的类似液体的基链尾之间滑动.
- 这种滑动发生在两个不同的平面上,这有助于异常低的摩擦.
- 这些发现为设计基于表面活性剂自组装的新型边界滑剂提供了洞察力.
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