多聚烯塑料的最新进展:聚乙烯和聚烯的转化和脱聚合技术
Acácio Silva de Souza1, Patricia Garcia Ferreira1, Iva Souza de Jesus1
1Programa de Pós-Graduação em Ciências Aplicadas a Produtos para a Saúde, Laboratório de Inovação em Química e Tecnologia Farmacêutica, Faculdade de Farmácia, Universidade Federal Fluminense, Rua Doutor Mario Vianna, 523, Santa Rosa, Niterói 24241-000, RJ, Brazil.
Molecules (Basel, Switzerland)
|January 11, 2025
概括
先进的回收方法,如热解和解,提供创新的解决方案,通过化学分解塑料成有价值的原料来打击塑料污染,支持循环经济和可持续发展目标.
科学领域:
- 环境科学与工程环境科学与工程
- 聚合物化学 聚合物化学
- 可持续材料 可持续材料
背景情况:
- 塑料污染是一个关键的全球问题,以石油为基础的聚合物透生态系统,并导致废物和温室气体排放.
- 塑料生产和消费的线性模式是不可持续的,需要超越传统机械回收的先进解决方案.
- 微塑料和可见塑料废物对环境和食物链的完整性构成重大威胁.
研究的目的:
- 审查和强调热解和解作为聚烯塑料的先进回收技术的潜力.
- 更新有关塑料化学回收的最新进展,技术,产品和产量的知识.
- 强调这些技术在减轻塑料污染和推进循环经济方面的作用.
主要方法:
- 专注于化学回收工艺,特别是热解和解,用于多聚烯的脱聚合.
- 对技术,产品流 (如热解油,合成气) 和效率的最新文献进行分析.
- 检查包括可扩展性,原料多样性,标准化和排放在内的挑战.
主要成果:
- 热解和解可以将塑料废物转化为可重复使用的材料和有价值的化学原料,支持循环经济原则.
- 这些方法提供了塑料在分子水平上的分解,为新产品和燃料创造了潜力.
- 重要的行业投资 (例如,牌,埃克森美) 旨在克服技术和环境障碍.
结论:
- 热解和解是塑料废弃物管理和减少环境影响的有希望的变革性战略.
- 这些先进的回收方法对于超越机械回收的局限性和实现可持续发展目标至关重要.
- 持续的研究和开发对于优化这些过程至关重要,以实现广泛采用和最大程度的环境效益.
相关概念视频
Free-Radical Chain Reaction and Polymerization of Alkenes
8.4K
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
8.4K
Types of Step-Growth Polymers: Polyesters
1.7K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
1.7K
Olefin Metathesis Polymerization: Overview
1.8K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
1.8K
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)
1.4K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
1.4K
Bioplastics
70
Bioplastics derived from microbial processes present a sustainable alternative to conventional petroleum-based plastics. Among these, polyhydroxyalkanoates (PHAs), particularly polyhydroxybutyrates (PHBs), have emerged as prominent candidates due to their biodegradability and biocompatibility. These polymers are synthesized by a variety of bacteria, such as Cupriavidus necator and Pseudomonas putida, which naturally accumulate PHAs as intracellular carbon and energy reserves, especially under...
70
Microbial Bioremediation of Plastics
131
Polyethylene terephthalate (PET) is a synthetic polymer widely utilized in the packaging industry, particularly for bottles and containers. Due to its chemical stability and durability, PET accumulates in the environment, contributing significantly to plastic pollution. It comprises repeating units of terephthalic acid and ethylene glycol, resulting in a semi-crystalline structure that is resistant to natural degradation processes.A notable breakthrough in plastic biodegradation came with the...
131


