基于Ceria的复合材料的增强光响应性能,具有丰富的氧气空隙
Yanping Li1,2, Xue Bian1,2, Hui Dong1,2
1Key Laboratory of Ecological Metallurgy of Multi-Metal Intergrown Ores of Ministry of Education, Shenyang 110819, China.
Molecules (Basel, Switzerland)
|January 11, 2025
概括
研究人员开发了含有高度氧空缺的-氧-硫 (Ce-O-S) 复合物. 这些材料表现出增强的光反应,用于光催化和阻光的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 固态化学 固态化学
背景情况:
- 在基基材料中的氧气空缺对于增强应用至关重要.
- 现有的方法在增加氧气空隙度方面存在局限性.
- 基于Ceria的材料在各种技术领域是必不可少的.
研究的目的:
- 为了合成新的-氧-硫 (Ce-O-S) 复合物.
- 研究氧气空缺对材料性能的影响.
- 探索阻光和光催化中的应用.
主要方法:
- 用于合成Ce-O-S复合材料的沉方法.
- 分析组合,结构,形态和光响应的特征化技术.
- 评估氧气空隙度和带隙能量.
主要成果:
- 由CeO2,Ce4O4S3和Ce2(SO4) 3组成的Ce-O-S复合物已经成功合成.
- 氧空缺与格子氧的最大摩尔比率达到了1.83.
- 频段间隙值降低到3.00 eV以下,将光响应延伸到蓝光区域.
结论:
- 在Ce-O-S复合材料中的高氧空置度显著提高了光响应.
- 对Ce (+3) 和S (-2) 的兴奋剂和协同效应有助于增加氧气空缺.
- Ce-O-S复合材料在阻光和光催化中的应用方面表现有前途.
相关概念视频
Porosity in Cement Paste
114
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
The balance of water to cement in the mix is...
114
Hydration of Cement
197
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
197


