多基粉含有丰富的基和独特的结构,可使 Zn 沉积均
Ming Song1, Zhaohe Guo1, Yan Xu1
1School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou 221018, China. xuyan8787@163.com.
概括
粉添加到硫酸电解质稳定了离子电池中的阳极,通过抑制副作用反应和促进均的沉积,提高电池性能.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 金属阳极对于离子电池 (ZIB) 至关重要,但会受到岩形成和副作用的影响,限制了它们的实际应用.
- 开发稳定和可逆阳极对于推进高性能ZIB技术至关重要.
研究的目的:
- 研究使用粉作为电解质添加剂来稳定ZIB中的阳极.
- 阐明粉减轻副作用并改善沉积的机制.
主要方法:
- 将粉添加到硫酸 (ZnSO4) 电解质溶液中.
- 带有粉和没有粉的阳极的电化学性能测试.
- 分析固体电解质介相 (SEI) 形成和沉积形态.
主要成果:
- 粉有效地重建了电解质的结网络,抑制了寄生虫的副作用反应.
- 粉的分子结构 (环,双螺旋) 与Zn2+离子强烈相互作用,调节它们的扩散和减少.
- 在阳极上的粉吸附促进了在 (002) 平面上均的 Zn 沉积,从而产生稳定的 SEI.
结论:
- 粉是一种高效的添加剂,用于稳定ZIB中的阳极.
- 粉的使用显著提高了阳极的电化学稳定性和可逆性,为商业化铺平了道路.
相关概念视频
Ionic Crystal Structures
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Metallic Solids
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Assembly of Cytoskeletal Filaments
Cytoskeletal filaments are polymeric forms of smaller protein subunits. However, individual cytoskeletal filaments may easily disassemble or associate with other similar filaments to form rigid structures. Microfilaments, made of actin monomers, rely on actin-binding proteins to form bundles and create networks of individual actin filaments. Microtubules rely on microtubule-associated proteins (MAPs) to form sturdy cylindrical structures. However, the proteins involved in forming complex...
The Structure of Intermediate Filaments
The intermediate filaments are one of three widely studied cytoskeletal filaments. They are so named as their diameter (10 nm) is in between that of microfilaments (7 nm) and the microtubules (25 nm). These filaments are highly stable and can remain intact when exposed to high salt concentrations and detergents. These filaments are responsible for providing stability and mechanical support to the cells. They also help in cell adhesion and maintaining tissue integrity.
Intermediate filaments...
Intermediate filaments...
Fibrous Proteins
Fibrous proteins are either long and narrow proteins or assemble to form long and thin structures. They contain repetitive units and usually consist of either alpha helices or beta sheets and, in rare cases, a mix of both. The amino acids in the primary structure often consist of repeating amino acid sequences. The role of fibrous proteins is primarily structural. Many are located in the extracellular matrix and are present in connective tissues to impart strength and joint mobility. They are...
Fineness Modulus
The fineness modulus (FM) of aggregate is a numerical index that measures the coarseness or fineness of the particles. It is calculated by adding the cumulative percentages of aggregate retained on each of a specified series of sieves and dividing the sum by 100.
Consider performing sieve analysis on sand through a set of ASTM sieves. The weight of aggregate retained in each sieve and pan placed at the bottom is recorded, as given in Column B of Table 1.
To determine the fineness modulus of...
Consider performing sieve analysis on sand through a set of ASTM sieves. The weight of aggregate retained in each sieve and pan placed at the bottom is recorded, as given in Column B of Table 1.
To determine the fineness modulus of...


