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在超酸性和氧化条件下Fe ((CO) 5的溶剂依赖反应性

Willi R Berg1, Marc Reimann2, Robin Sievers1

  • 1Institut für Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34-36, D-14195 Berlin, Germany.

Journal of the American Chemical Society
|January 14, 2025
PubMed
概括

溶剂决定了五碳酸铁与五的反应. 在无水HF中的反应产生质子化铁化物复合物,而在液体SO2中的反应产生双核铁碳基离子.

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