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探索无金属原始爆炸物的最大启动能力

Qiong Yu¹, Zhiyuan Zheng¹, Zhenxin Yi¹

¹School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

Journal of the American Chemical Society

|January 15, 2025

概括

研究人员开发了1,8-diazido-bis ([1,2,4]triazole) [4,3-b:3

科学领域:

能量材料科学
化学工程
材料科学

背景情况:

酸 (LA) 是一种常见的初级爆炸物,但存在毒性和安全问题.
监管限制促使人们需要更安全的无替代品.
目前的研究重点是开发具有更高安全性和性能的下一代初级爆炸物.

研究的目的:

合成和描述一种新型无原爆剂,1,8-diazido-bis([1,2,4]triazolo) [4,3-b:3',4'-f][1,2,4,5]tetrazine (DATTY).
与酸相比,评估DATTY的安全性,热稳定性和启动能力.
建立DATTY作为潜在的替代化物在爆炸性应用.

主要方法:

1,8-diazido-bis (([1,2,4]triazole) [4,3-b:3',4'-f][1,2,4,5]tetrazine (DATTY) 的合成方法.
测量含量,摩擦灵敏度和形成热量.
通过最小初级电荷 (MPC) 测试评估启动能力.
测定爆炸速度 (vD).

主要成果:

DATTY的含量很高 (80.3%),在环境条件下保持稳定.
与酸 (0.3N) 相比,DATTY的摩擦灵敏度明显较低.
DATTY具有较高的内热形成热量 (6.533 kJ g-1).
通过低MPC的1毫克 (相对于LA的10毫克) 证明了异常的启动能力.
破纪录的爆炸速度 (vD = 8835 m s-1).

结论:

达蒂是一种有前途的无原爆,具有卓越的安全性和启动性能.
这项研究确立了DATTY作为下一代初级爆炸物的新基准.
DATTY提供了一个更安全,更有效的替代化物,解决了环境和处理问题.

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