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柱体[5]arene 附加Pyrene Schiff基:光物理,聚合诱导发射和图酸识别

Subhasis Ghosh¹, Kumaresh Ghosh¹

¹Department of Chemistry, University of Kalyani, Kalyani, Nadia, 741235, India.

Chemistry, an Asian journal

|January 15, 2025

概括

我们合成了一种基于arene的新型copillar[5]pyrene Schiff基,表现出聚合诱导排放 (AIE). 这种化合物可以选择性地检测溶液中的皮克酸 (PA),显示出用于传感应用的潜力.

科学领域:

超分子化学超分子化学
有机合成有机合成
材料科学材料科学材料科学

背景情况:

配角体[5]体是具有可调节性质的宏循环宿主.
皮雷尼衍生物以其光物理特性而闻名.
船基连接提供了多功能合成路线和功能化.

研究的目的:

为了合成和表征一种新型的辅极[5]arene-based pyrene Schiff 基.
调查其光物理特性,包括聚合诱导排放 (AIE).
探索其在选择性检测酸芳香化合物的应用.

主要方法:

使用NMR,FT-IR和质谱学进行合成和表征.
光物理研究包括紫外线吸收和光光谱学.
密度函数理论 (DFT) 计算用于电子结构分析.
使用动态光散射 (DLS) 和时间相关单光子计数 (TCSPC) 的聚合研究.

主要成果:

合成的化合物在水性THF和DMF中表现出聚合诱导的排放 (AIE).
鉴定出疏水效应是聚合物形成的驱动力.
聚合状态选择检测到低检测极限 (1.62×10−7 M) 的皮克酸 (PA).
在与PA相互作用时观察到显著的光火.

结论:

辅体[5]arene 基的 pyrene Schiff 基体表现出有前途的 AIE 特性.
该化合物可用于选择性和敏感的光检测皮克酸.
这项工作突出了为化学传感应用量身定制的超分子结构的潜力.

关键词:

聚合诱导的排放量聚合诱导的排放量副体[5]arene是一种费特·弗雷特 (FRET FRET) 是一家在美国的船只.皮克里酸是什么?皮克里酸是什么?皮勒尼斯海峡船只基地

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