具有快速固态硫反应的全固态Li-S电池
Huimin Song1, Konrad Münch2,3, Xu Liu1
1Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, School of Materials Science and Engineering, Peking University, Beijing, China.
Nature
|January 15, 2025
概括
这项研究引入了一种全固态硫电池的酸玻璃相固体电解质. 这一突破使得固体-固体硫氧化还原反应快速,提高了电池的性能和周期寿命.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 全固态硫电池 (ASSLSB) 为下一代储能提供高能耗,安全性和低成本.
- 在ASSLSB中的低速性能和短周期寿命归因于三相边界的缓慢的固体-固体硫氧化还原反应 (SSSRR).
研究的目的:
- 通过增强缓慢的SSSRR来解决ASSLSB的局限性.
- 开发一种新型的固体电解质,可以作为减氧介质加速SSRR.
主要方法:
- 硫酸 (LBPSI) 玻璃相固体电解质 (GSEs) 的开发.
- 使用固体电解质中的I-/I2/I3-可逆氧化还原作为表面氧化还原介质.
- 研究氧化还原介质对活性位点密度和反应动力学的影响.
主要成果:
- LBPSI GSE促进了快速的SSRR,显著增加了活跃地点的密度.
- ASSLSB在2C时显示出1497mAhg-1硫的超快充电能力,在20C时保持784mAhg-1硫.
- 在极端速率 (432mAhg-1硫在150°C,60°C) 和循环稳定性 (80.2%在5°C的25,000个循环中保持) 中观察到异常性能.
结论:
- 开发的LBPSI GSE有效地调解SSRR,克服了ASSLSB的先前局限性.
- 这种以氧化还原为媒介的方法使ASSLSB具有高速率的能力和卓越的循环稳定性.
- 这些发现为先进,高能耗和安全的ASSLSB铺平了道路.
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