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Updated: Jun 1, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
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Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization

Published on: August 6, 2018

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静电调节激素加和原子抽象反应与二极子激素离子

Oisin J Shiels1, Samuel C Brydon2, Berwyck L J Poad2

  • 1Molecular Horizons and School of Chemistry and Molecular Bioscience, University of Wollongong Wollongong New South Wales 2522 Australia adamt@uow.edu.au.

Chemical science
|January 17, 2025
PubMed
概括

定向电场 (OEF) 通过调整反应性和选择性来精确控制激进反应. 这项研究表明,在分子支架上战略地放置的带电组如何使化学转换的可预测操纵能够实现更绿色的合成.

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Radical Reactivity: Overview

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Radicals can be formed by adding a radical to a spin-paired molecule. This is typically observed with unsaturated species, where the addition of a radical across the π bond leads to the production of a new radical by dissolving the π bond. For example, the addition of a Br radical to an alkene yields a carbon-centered radical.
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Along with electronic...
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