使用酸氧同位素识别农业排水和浸出物中的溶解反应来源
Rose C K Mumbi1, Mark R Williams2, William I Ford3
1USDA ARS, National Soil Erosion Research Laboratory, West Lafayette, IN 47907, United States of America; Purdue University, Department of Agronomy, West Lafayette, IN 47907, United States of America.
Journal of contaminant hydrology
|January 17, 2025
概括
追踪农业 (P) 损失对于淡水保护至关重要. 氧-18签名 (δ18OPO4) 有效地识别了最近应用的肥料作为应用后立即P损失的主要来源.
科学领域:
- 环境科学 环境科学
- 农业科学 农业科学
- 同位素地球化学 同位素地球化学
背景情况:
- 来自肥料和土壤的农业 (P) 损失有助于淡水污染.
- 区分P源对于有效的管理实践来减少环境风险至关重要.
- 了解P流失的来源对于有针对性的减缓策略至关重要.
研究的目的:
- 量化新 (肥料) 与旧 (土壤) 在农业排水和液中的损失.
- 为了评估酸盐 (δ18OPO4) 的氧-18签名作为P来源的标记物的实用性.
- 评估施肥时间对P损失动态的影响.
主要方法:
- 在施肥前和施肥后,在土壤柱上进行了实验室降雨模拟.
- 酸盐 (δ18OPO4) 在肥料,土壤,排水和液中的氧-18签名的分析.
- 归因于直接肥料P损失的溶解反应性P (DRP) 负载的量化.
主要成果:
- 溶解反应性P (DRP) 度在排水和液中显著增加,在施加肥料后立即显著增加.
- 排水和液中的 δ18OPO4 标记与肥料标记密切匹配,表明>90%的肥料直接P损失.
- 随后的降雨事件显示DRP降低和不同的液 δ18OPO4签名,使源归因复杂化.
结论:
- 酸盐 (δ18OPO4) 的氧-18特征是一个有前途的工具,可以在短期内追踪直接的肥料P损失.
- 由于潜在的非生物和生物P循环影响,解释同位素签名在后来的事件中变得具有挑战性.
- 虽然对于应用后的直接损失有效,但在使用 δ18OPO4 来追踪 P 源在较长时间内仍然存在挑战.
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