植物捕获的火山气溶:对纳米粒子及其化学成分的研究
Marine Gelin1, Mickaël Tharaud1, Marc F Benedetti1
1Université Paris Cité - Institut de Physique du globe de Paris, CNRS, F75005 Paris, France.
The Science of the total environment
|January 17, 2025
概括
火山纳米粒子 (NP) 的特征是使用先进的质谱学. 植物有效地在烟雾附近取样这些NP,揭示了多元素和微量元素组成,其中一些具有潜在的生态影响.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 分析化学 分析化学
背景情况:
- 纳米粒子 (NP) 由于它们的反应性和可移动性,造成环境和健康风险.
- 火山是大气NP的重要自然来源,但它们的环境命运仍未得到充分研究.
- 单粒子感应合等离子体质谱学 (spICP-MS) 的进展使得详细的NP特征化成为可能.
研究的目的:
- 来自瓜德罗普的La Soufrière火山的火山纳米粒子 (NP) 的特征.
- 为了调查在活跃和不活跃的火山时期发出的NP.
- 评估植物作为火山NPs附近烟雾的自然采样者.
主要方法:
- 对古代火山灰和烟雾凝结物的分析.
- 使用植物作为空气中的NP的被动采样.
- 在单颗粒模式 (spICP-ToF-MS) 中使用的ICP-MS飞行时间用于多元元素分析.
- 应用了NP数据处理的等级聚合集群.
主要成果:
- 确定了三种多元素NP (Al+Si,Al+Fe,Ti+Al) 和三种单元素NP (Al,Si,Fe) 的类型.
- 在Sphagnum孔水中检测到的微量元素NP (例如Sr-Ce-La,CeLa,Cr,Cu,Zn).
- 已确认的植物作为有效的采样者,捕获效率受叶子特征的影响.
- 与火山,碎石和大气材料的NP元素比率进行比较,以确认火山起源.
结论:
- 植物可以在极端环境中作为火山纳米颗粒的有效生物监测器.
- 火山活动释放出各种NP,包括潜在的有毒微量元素.
- spICP-ToF-MS是一个强大的工具,用于环境样本中描述复杂的NP混合物.
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