易于用水合成的铁化酸框架作为可持续离子电池的高能和高功率阴极
Víctor Durán-Egido1, James P Darby2, Matthew J Cliffe3
1Inorganic Chemistry Department, Universidad Complutense de Madrid, 28040, Madrid, Spain.
Angewandte Chemie (International ed. in English)
|January 18, 2025
概括
新的基于铁的金属有机框架 (MOF) 提供高性能,低成本的电池阴极. 这些材料证明了,和的竞争性储能能力,推动了可持续的能源解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 固态化学 固态化学
背景情况:
- 高性能电池阴极对于储能至关重要.
- 金属有机框架 (MOF) 是一个有希望的低成本,高容量的正极材料.
- 铁-化物-水框架是在温和的水性条件下合成的.
研究的目的:
- 从廉价的过渡金属和有机配体开发新的MOF.
- 为了研究铁-化物-水框架的结构和电化学特性.
- 评估它们作为可持续电池的阴极的潜力.
主要方法:
- 铁-化物-水框架的水性合成.
- 使用ab initio随机结构搜索,电子衍射和瑞特维尔德精细化进行结构性表征.
- 在Li,Na和K半电池中进行电化学测试.
- 磁性,莫斯尔和拉曼光谱学.
主要成果:
- 合成了一种新的超分子MOF ([Fe2(CAN) 3 ((H2O) 4)) 和一个二维蜂MOF ([Fe2 ((CAN) 3))).
- 2D MOF表现出不寻常的ABC层堆叠,并且包含HS-Fe3+和CAN2-.
- 可逆插入容量>4Li+/f.u.u. 的可逆插入容量. 在2.59V与Li+/Li.Li.相对应的电压下实现.
- [Fe2(CAN) 3]在半电池中显示了563Wh/kg的特定能量和446W/kg的功率.
- 在Na (394Wh/kg) 和K (421Wh/kg) 半电池中也观察到具有竞争力的性能.
结论:
- 铁-化物-水框架是可行的,低成本的正极材料.
- 合成的MOF为Li,Na和K电池提供了具有竞争力的电化学性能.
- 这些材料代表了可持续能源存储技术的重大进步.
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