在高超冷玻璃形成金属融中原子波动的合作性
Jürgen E K Schawe1, Min Kyung Kwak1,2, Mihai Stoica1
1Laboratory of Metal Physics and Technology, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland.
The journal of physical chemistry letters
|January 21, 2025
概括
超冷却的金属玻璃表现出影响其行为的动态异质性. 合作性原子重排的相关长度独立于合金成分,在玻璃过渡附近保持不变.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 物理化学 物理化学
背景情况:
- 超冷却的形成玻璃的金属表现出由合作的原子波动驱动的复杂行为.
- 融化的动态异质性导致动态集群的形成,或合作重组区域 (CRR).
研究的目的:
- 为了确定特定金属玻璃成型器中CRR的宏观动力学和相关长度 (ξ).
- 调查合金组成对CRR和玻璃过渡行为的影响.
主要方法:
- 快速差异扫描热度计 (DSC) 在玻璃过渡温度附近使用.
- 分析的重点是推导合作性原子运动的相关长度 (ξ).
主要成果:
- 合金组成会影响α放松,玻璃化动力学和脆弱性,但不会影响合作原子运动的相关长度.
- 对于Pt-Cu-Ni-P和Pd-Cu-Ni-P金属玻璃,在玻璃过渡时,相关长度 (ξ) 发现大约为3nm.
- ξ的温度依赖与α-放松的激活能量相关,解释非Arrhenius行为.
结论:
- 合作性原子重排的相关长度是这些金属玻璃的普遍性质,独立于特定的合金成分.
- 了解 ξ 对于解释在玻璃过渡附近的超冷金属融中观察到的非阿雷尼乌斯动态至关重要.
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