能量聚合用于照明升级转换多色辐射基于Ho3+离子
Xiaoyu Meng1,2,3, Tao Shen1, Wenbo Zhang1
1School of Materials Science& Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China.
ACS applied materials & interfaces
|January 21, 2025
概括
研究人员使用新型材料和有机染料增强了用荷添加的上转化纳米粒子 (UCNPs) 的发光. 这些工程UCNPs在水中显示强烈的红光辐射,对生物医学应用有希望.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 光子学 是一个光子学.
背景情况:
- 添加兰胺的升级转换发光纳米粒子 (UCNPs) 提供独特的反斯托克斯转移和光稳定性.
- 基于 (Ho3+) 的UCNP具有复杂的能量水平,限制了发光效率.
研究的目的:
- 为了增强Ho3+离子的向上转换发光强度.
- 改进UCNP中的光子吸收和能源利用效率.
主要方法:
- 主体材料和敏感剂的合理设计.
- 加入有机染料作为外部能量天线.
- 在不同的溶液环境中对光发的研究.
主要成果:
- 通过优化材料选择和染料天线实现了高效的吸收和能量传输.
- 由于不同的氧振动效应,观察到多色发光.
- 在水溶液中表现出强烈的红光升高转化.
结论:
- 开发的策略有效地提高了Ho3+升级的光效应.
- 这些纳米材料表现出取决于环境的发光特性.
- 在水溶液中发出大量的红光,这表明生物医学成像和色度测量具有重大潜力.
相关概念视频
Colors and Magnetism
11.5K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.5K
The Antenna Complex
5.9K
Plants and other photosynthetic organisms comprise pigments capable of absorption of direct sunlight. These pigments are present in the reaction center - the main site of photochemical reactions as well as in the antenna complex. Under average light conditions, the rate at which reaction center pigments absorb light is far below the electron transport chain's capacity. As a result, the reaction center alone cannot provide enough energy to drive photosynthesis. The photosynthetic efficiency...
5.9K
Photoluminescence: Fluorescence and Phosphorescence
1.5K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
1.5K
Photoluminescence: Applications
369
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
369
Emission Spectra
50.4K
When solids, liquids, or condensed gases are heated sufficiently, they radiate some of the excess energy as light. Photons produced in this manner have a range of energies, and thereby produce a continuous spectrum in which an unbroken series of wavelengths is present.
50.4K


