在水空气界面上,和多基基物质 (PFAS) 之间的相互作用
Amélie C Lemay1, Ian C Bourg1,2
1Department of Civil and Environmental Engineering, Princeton University, Princeton, New Jersey 08544, United States.
Environmental science & technology
|January 21, 2025
概括
由于强大的内部吸引力,在水-空气接口上形成有序的涂层的Per-和多基物质 (PFAS). 了解这些相互作用对于预测PFAS命运和改善水处理策略至关重要.
科学领域:
- 环境化学环境化学
- 表面科学是一门学科.
- 计算化学计算化学
背景情况:
- 和多基基物质 (PFAS) 是饮用水中普遍存在的污染物.
- 标准的水处理方法在去除PFAS方面往往是无效的.
- PFAS在水空气界面积聚,影响它们的环境行为和修复.
研究的目的:
- 为了研究有机负载对水空气界面的PFAS吸附的影响.
- 阐明控制PFAS在接口上的积累的分子机制.
主要方法:
- 使用了分子动力学模拟.
- 用不同的PFAS接口密度进行了模拟.
- 分析了PFAS分子之间的相互作用以及与其他界面组件的相互作用.
主要成果:
- 吸附的PFAS形成有序的界面涂层,由强烈的相互相互作用驱动.
- perfluoroalkyl 链之间的吸引力和头组之间的静电相互作用是关键.
- 这些相互作用可以导致疏水吸引力和库伦反射的几乎取消.
- PFAS吸附对接口涂层的组成和密度敏感.
结论:
- 这项研究解释了吸附同热体中看似最小的相互作用与对界面条件高度敏感性的悖论.
- 了解这些界面相互作用对于准确预测PFAS命运和运输至关重要.
- 这种知识可以为设计更有效的PFAS整治技术提供信息.
更多相关视频
07:06Investigating Long-Distance Transport of Perfluoroalkyl Acids in Wheat via a Split-Root Exposure Technique
Published on: September 28, 2022
1.5K
07:01Preparation of Hollow Polystyrene Particles and Microcapsules by Radical Polymerization of Janus Droplets Consisting of Hydrocarbon and Fluorocarbon Oils
Published on: January 25, 2018
9.9K
相关概念视频
Halogens
18.3K
Group 17 elements, known as halogens, are nonmetals. At room temperature, fluorine and chlorine are gases, bromine is a liquid, and iodine a solid. Astatine is a highly unstable radioactive element, so currently, most of its properties are unknown due to its short half-life. Tennessine is a synthetic element also predicted to be in this group.
18.3K
Intermolecular Forces and Physical Properties
20.4K
20.4K
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
43.8K
Intermolecular forces are attractive forces that exist between molecules. They dictate several bulk properties, such as melting points, boiling points, and solubilities (miscibilities) of substances. Molar mass, molecular shape, and polarity affect the strength of different intermolecular forces, which influence the magnitude of physical properties across a family of molecules.
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...
43.8K
Intermolecular Forces
57.5K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
57.5K
