具有机械弹性和高效率的柔性矿太阳能电池与酸用于表面粘附和减压
Yumeng Xu1, Siyu Zhang1, Haidong Yuan2
1State Key Laboratory of Wide-Bandgap Semiconductor Devices and Integrated Technology, Faculty of Integrated Circuit, Xidian University, 710071 Xi'an, China.
ACS nano
|January 22, 2025
概括
乙酸通过减少压力和消极缺陷来增强柔性矿太阳能电池 (FPSC). 这提高了效率,并改善了下一代太阳能技术的机械耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 固态物理 固态物理
背景情况:
- 灵活的矿太阳能电池 (FPSC) 在功率与重量比和制造方面具有优势.
- 主要挑战包括低于最佳的效率和机械稳定性,阻碍了广泛应用.
研究的目的:
- 调查使用乙酸 (OAAc) 作为对矿薄膜的表面处理.
- 提高FPSC的效率和机械耐用性.
主要方法:
- 将OAAc与柔性分子链结合到矿膜上.
- 薄膜和设备性能的表征,包括应力释放.
- 有限元模拟以确认机械释放层的行为.
- 通过形成能量计算进行缺陷被动化分析.
主要成果:
- OAAc充当机械释放层,减轻拉伸应力.
- 通过OAAc被动化,可显著降低矿中的缺陷状态 (如空位,反位).
- OAAc处理将开放电路的电压提高到1.196V.
- 设备效率在刚性基板上提高到25.47%,在柔性基板上提高到23.12%.
- 灵活的设备在8000个曲周期后保持74%的效率.
结论:
- OAAc是提高FPSC性能和稳定的有效添加剂.
- OAAc的灵活分子结构有助于应力释放和缺陷被动化.
- 通过OAAc的修改,可以获得高质量的矿膜,其光电子性能得到改善.
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