具有抗和高强度的pH调节的甲基醇改性基酸盐水凝,用于可穿戴式应变传感器
Mingxue Xia1, Xiao Meng1, Limin Lin1
1School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China.
International journal of biological macromolecules
|January 22, 2025
概括
这项研究介绍了一种用于柔性电子产品的新型防液凝,其显著的伸展性和耐度低至-42.21°C,在寒冷环境中可靠性能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 生物医学工程 生物医学工程
背景情况:
- 基于水凝的柔性电子产品具有出色的性能,但受到冷引起的性能降低的影响.
- 开发强大的防水凝,在寒冷条件下提供长期稳定性仍然是一个重大挑战.
研究的目的:
- 设计和制造具有增强防性能和机械性的双重物理交联水凝.
- 为了研究pH控制的铁离子协调对水凝性能的影响.
主要方法:
- 采用两步制造方法,制造出一个聚乙醇/藻酸盐-移植多巴胺/铁离子 (PVA/SA-g-DA/Fe3+) 水凝.
- 通过调整浸泡溶液的pH值来调整catechol组和铁离子之间的协调.
主要成果:
- 由此产生的PVA/SA-g-DA/Fe3+水凝表现出优越的伸展性,性和显著的耐性,温度低至-42.21°C.
- 液凝表现出稳定且准确的应变传感能力,用于监测正常和低温的人类活动.
结论:
- 开发的水凝为在寒冷环境中稳定运行电子设备提供了有前途的解决方案.
- 这项工作为设计在极端温度条件下用于信号检测的先进水凝提供了战略方法.
相关概念视频
Determining the pH of Salt Solutions
The pH of a salt solution is determined by its component anions and cations. Salts that contain pH-neutral anions and the hydronium ion-producing cations form a solution with a pH less than 7. For example, in ammonium nitrate (NH4NO3) solution, NO3− ions do not react with water whereas NH4+ ions produce the hydronium ions resulting in the acidic solution. In contrast, salts that contain pH-neutral cations and the hydroxide ion-producing anions form a solution with a pH greater than 7. For...
pH
The potential of hydrogen (pH) is a measure of the acidity or basicity of a water-based solution determined by the concentration of hydronium ions (H3O+). In one liter of pure water at neutral pH, there are 1×10−7 moles of hydronium ions. However, the extensive range of hydronium ion concentrations present in water-based solutions makes measuring pH in moles cumbersome. Therefore, a pH scale was developed to convert moles of hydronium ions into the negative logarithm of the hydronium ion...
Titration of a Weak Base with a Strong Acid
The titration curve of a weak base like ammonia with a strong acid like hydrochloric acid is the mirror image of the titration curve of a weak acid with a strong base.
Using the ICE table and substituting the Kb value, we calculate the initial pH of 50 mL of 0.1 M ammonia to be 11.11. Addition of 25 mL of 0.1 M hydrochloric acid to this solution of ammonia results in a buffer with an equal concentration of ammonia and ammonium ions. The pH of this buffer can be calculated by substituting these...
Using the ICE table and substituting the Kb value, we calculate the initial pH of 50 mL of 0.1 M ammonia to be 11.11. Addition of 25 mL of 0.1 M hydrochloric acid to this solution of ammonia results in a buffer with an equal concentration of ammonia and ammonium ions. The pH of this buffer can be calculated by substituting these...
Potentiometry: Membrane Electrodes
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at the...
Conductometric Titrations: Strong Acid-Base and Weak Acid-Base Titrations
In acid-base titrations, conductance measurements are utilized to detect the endpoint. This method is grounded on the fact that electrical conductance relies on the number and mobility of ions. For instance, consider titrating strong acid HCl with a strong NaOH base. Initially, the HCl in the conductivity vessel conducts electricity due to the presence of hydrogen ions and chloride ions. As NaOH is gradually added from the burette, the fast-moving hydrogen ions are replaced by slower-moving...
Acid-Base Balance
The human body maintains a narrow pH range regulated through acid-base balance. This balance is crucial as changes in the hydrogen ion concentration can disrupt cell membrane stability, alter protein structures, and change enzyme activities. The normal pH of arterial blood is 7.4, venous blood and interstitial fluid is 7.35, and intracellular fluid averages 7.0.
When the pH of arterial blood rises above 7.45, it results in a condition called alkalosis. Conversely, a drop below 7.35 leads to...
When the pH of arterial blood rises above 7.45, it results in a condition called alkalosis. Conversely, a drop below 7.35 leads to...


