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相关概念视频

Nuclear Stability03:18

Nuclear Stability

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Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together...
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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes02:14

Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes

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The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were  initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
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Introduction to Mechanisms of Enzyme Catalysis01:13

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For many years, scientists thought that enzyme-substrate binding took place in a simple "lock-and-key" fashion. This model stated that the enzyme and substrate fit together perfectly in one instantaneous step. However, current research supports a more refined view scientists call induced fit. The induced-fit model expands upon the lock-and-key model by describing a more dynamic interaction between enzyme and substrate. As the enzyme and substrate come together, their interaction causes...
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Thermodynamics: Activity Coefficient01:24

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Activity is the measure of the effective concentration of the species in solution. It can be expressed as the product of the molar concentration of the species and its activity coefficient. The activity coefficient is a dimensionless quantity and depends on the total ionic strength of the solution.
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
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Understanding the stability of equilibrium configurations is a fundamental part of mechanical engineering. In any system, there are three distinct types of equilibrium: stable, neutral, and unstable.
A stable equilibrium occurs when a system tends to return to its original position when given a small displacement, and the potential energy is at its minimum. An example of a stable equilibrium is when a cantilever beam is fixed at one end and a weight is attached to the other end. If the weight...
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相关实验视频

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Preparation and 3D Tracking of Catalytic Swimming Devices
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核心催化剂的活性和稳定性起源:不可忽视的原子扩散行为.

Yuanyuan Xue1, Letian Chen2, Lijuan Zhang1

  • 1Laboratory of Advanced Materials, Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University Shanghai 200438 China gfzheng@fudan.edu.cn.

Chemical science
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概括

核心外催化剂显示出出色的氧气减排和进化反应. 动态结构演变,包括原子扩散,是这些电催化剂活动和长期稳定的关键.

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科学领域:

  • 电触媒溶解是一种电触媒.
  • 材料科学 材料科学 材料科学
  • 表面化学 表面化学

背景情况:

  • 核心外催化剂在氧减少反应 (ORR) 和氧演化反应 (OER) 中表现出有希望的性能.
  • 了解它们的活动和持久性的起源通常依赖于静态结构分析,可能会忽视动态过程.

研究的目的:

  • 阐明ORR和OER的NiFe@NC核心催化剂的活性结构和稳定机制.
  • 调查动态结构演变在电催化剂性能和寿命中的作用.

主要方法:

  • 作为一个模型系统,使用了涂有添加碳外 (NiFe@NC) 的NiFe合金.
  • 结合常量电位计算,分子动力学模拟和实验验证.
  • 在电化学反应期间分析了原子扩散行为.

主要成果:

  • 合金核心和碳外之间的协同效应促进Fe-N-C活性部位的形成.
  • 核心作为一个储存库,补充金属位置,确保长期稳定性.
  • 在ORR/OER期间,原子扩散对于活跃点的动态形成和再生至关重要.

结论:

  • 动态结构演变和重建对于核心电催化剂的高活性和稳定性至关重要.
  • "弹药库"和"自动装载器"的类比强调了核心和外之间的相互作用,以实现持续的性能.
  • 这项研究为设计用于能源应用的强大和高效的电催化剂提供了基本的见解.