开发可挤出的水凝,基于碳氧甲基纤维素 - 凝复合物的协同化物
Hamid Gharanjig1, Hossein Najaf Zadeh1,2, Campbell Stevens1
1School of Product Design, University of Canterbury, Christchurch 8041, New Zealand.
Gels (Basel, Switzerland)
|January 24, 2025
概括
这项研究探讨了用于3D打印的碳素甲基纤维素 (CMC) - 凝协体. 优化的比率和pH值提高了打印能力,显示了在先进应用中精确材料沉积的潜力.
科学领域:
- 生物材料科学 生物材料科学
- 聚合物化学 聚合物化学
- 添加剂制造 添加剂制造 添加剂制造
背景情况:
- 复杂的协体是通过相反电荷的聚合物之间的静电相互作用形成的.
- 碳氧甲基纤维素 (CMC) 和凝是生物相容的聚合物,具有各种应用的潜力.
- 3D打印需要具备特定的气质和机械性能的材料才能成功制造.
研究的目的:
- 为了研究碳甲基纤维素 (CMC) - 凝复合物的3D挤压打印.
- 描述CMC-凝比率,pH值和生物聚合物度对凝聚和打印能力的影响.
- 评估开发的水凝系统的风学特性,粘度和打印质量.
主要方法:
- 制备和分析各种CMC-凝联合合物水凝.
- 度测量以确定最佳的同化pH范围.
- 同焦点激光扫描显微镜 (CLSM) 和扫描电子显微镜 (SEM) 用于结构分析.
- 风病学特征包括剪切粘度和剪切恢复.
- 在受控温度下进行3D挤压打印试验.
主要成果:
- 最佳的协发生在pH值3.7和5.6之间,被度和显微镜证实.
- 在CMC-凝水凝中,表现出伪塑性行为,粘度降低,化率更高.
- 与纯格拉水凝 (29N) 相比,同体的粘度显著降低 (1-15N).
- 1:15的CMC-凝比率显示出出色的剪切恢复和一致的3D打印质量.
- 所有样品的挤出成功,在6%的生物聚合物度下1:15的比率显示出最佳结果.
结论:
- 在CMC-凝协系统是一个有前途的生物材料3D挤出打印.
- 材料特性如粘度,粘度和可打印性可以通过调整CMC-凝比率和pH来调整.
- 该系统为需要精确沉积和可调节材料特性的应用提供了潜力.
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