一个比较的动力学和热力学吸附研究甲蓝及其对应染料在纸上的模拟染料
Andrea Bogyor1, Alexandra Ana Csavdari1,2, Tamás Lovász1,3
1Department of Chemical Engineering, Babeş-Bolyai University of Cluj-Napoca, Arany Janos Street 11, 400028 Cluj-Napoca, Romania.
International journal of molecular sciences
|January 25, 2025
概括
商用过纸通过物理吸附有效地吸附甲基蓝 (MB),而其模拟物 (MBI) 更适合过. 这两种染料都表现出扩散控制的吸附过程.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
背景情况:
- 水中的染料污染给环境带来了挑战.
- 吸附材料对于从水溶液中去除染料至关重要.
研究的目的:
- 为了比较甲蓝 (MB) 和其模拟物 (MBI) 在商用过纸上的吸附行为.
- 为了阐明两种染料的吸附动力学,同热量和热力学.
主要方法:
- 使用水溶液和商用过纸进行批量吸附实验.
- 使用七种模型和统计指标进行动态建模.
- 使用11个模型进行异热模拟.
- 吸附过程的热力学分析.
主要成果:
- 伪二次,双指数和双线韦伯-莫里斯模型最好地描述了吸附动力学.
- 对两种染料来说,吸附遵循了两个扩散控制的步骤.
- 弗洛因德利希等热量最适合数据,表明物理吸收.
- 热力学上有利于MB吸附,而MBI吸附则受到硬质阻碍.
- 这两种过程都是外热的,随机性减少.
结论:
- 商用过纸适合通过物理吸收保留MB.
- 过纸用于MBI的过/净化作用.
- 了解吸附机制是有效的染料去除策略的关键.
关键词:
吸附吸附是一种吸附.吸附性异热体是一种吸附性异热体.吸附动力学的吸附动力学吸附热力学 吸附热力学过纸是一种过纸.甲基烯蓝色是什么意思甲蓝的模拟物是甲蓝的模拟物.模型质量统计指标 模型质量统计指标更多相关视频
相关概念视频
Filtration
767
Filtration is a physical separation process that involves passing a suspension through a porous medium to separate solids from fluids. During filtration, solids collect on the porous medium while liquids, also collectively known as the filtrate, pass through. The filtration medium is selected based on the filtration purpose, quantity, and nature of the precipitate. The general criteria for a suitable filtering medium are that it is inert, mechanically strong, nonabsorbent toward dissolved...
767
Analyte Adsorption and Distribution
595
In certain chromatographic separations, solutes transfer between the mobile phase and the stationary phase via sorption, which typically refers to the process of adsorption. For many chromatographic systems, the sorption process often depends on the polarity of the compounds—an expression of the overall dipole moment within the molecule. During the separation process, there is competition between the solute and solvent for adsorption to the stationary phase. Highly polar compounds and...
595
Dialysis
578
Dialysis is a diffusion-based purification process that separates analyte molecules from a complex matrix. This is accomplished by allowing molecules in the solution to pass through a semipermeable membrane into a liquid on the other side. The membrane is usually made of cellulose acetate or cellulose nitrate, and the second liquid must be miscible with the solution. Ions (e.g., chloride or sodium) or organic molecules (e.g., glucose) can pass through the membrane pores, which generally have...
578


