用L-酸修饰的玻璃/聚层材 - - 对易燃性和烟雾排放的影响
Adriana Dowbysz1, Mariola Samsonowicz1, Bożena Kukfisz2
1Department of Chemistry, Biology and Biotechnology, Bialystok University of Technology, Wiejska 45A Street, 15-351 Bialystok, Poland.
Materials (Basel, Switzerland)
|January 25, 2025
概括
L-酸 (ArgPA) 提高了玻璃纤维增强聚层 (GFRPs) 的消防安全. 与商业替代品相比,这种生物基阻燃剂提高了自灭特性,并降低了烟雾密度.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 消防安全工程 消防安全工程
背景情况:
- 玻璃纤维增强聚合物 (GFRP) 广泛使用,但存在火灾风险.
- 为GFRP开发有效和可持续的阻燃剂至关重要.
研究的目的:
- 调查L-酸 (ArgPA) 作为生物基阻燃剂对GFRP的疗效.
- 评估ArgPA对易燃性和烟雾生成特性的影响.
主要方法:
- 要素分析,FTIR和热重力测量分析 (TGA) 用于ArgPA的表征.
- 用于GFRP制剂的手工铺设方法,含有不同ArgPA含量 (重量5%-15%).
- 限制氧气指数 (LOI) 和烟雾密度测试,以评估消防性能.
主要成果:
- 添加ArgPA在GFRP上形成了一层保护性烧焦层.
- LOI从20.73%增加到24.55%的GFRPs与15%的ArgPA,实现了自灭的分类.
- 与商业APP相比,ArgPA修饰的GFRP的特定烟雾密度较低,尽管烟雾产生增加.
结论:
- 作为一种生物基阻燃剂,ArgPA显示出显著的潜力,可以提高GFRP的消防安全性.
- 烧焦效应和分解产品有助于提高耐火性.
- 阿格帕为传统阻燃剂提供了一个有前途的替代品.
相关概念视频
Flame Photometry: Overview
443
Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
443
Flame Photometry: Lab
211
In a flame photometer, when a solution like potassium chloride is aspirated into the flame, the solvent evaporates, leaving behind dehydrated salt. This salt dissociates into free gaseous atoms in their ground state. Some of these atoms absorb energy from the flame, leading to their excitation. The excited atoms return to the ground state, emitting photons at characteristic wavelengths. Because only electronic transitions are involved, the resulting emission lines are very narrow. The intensity...
211
Types of Step-Growth Polymers: Polyesters
2.2K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the...
2.2K
Atomic Emission Spectroscopy: Interference
163
In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
163
Variables Affecting Phosphorescence and Fluorescence
479
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
479
Photoluminescence: Applications
368
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
368


