通过使用热塑性聚合物进行修改,开发生物基和可回收的环氧粘合剂
Riccardo Miranda1, Marco Luciano1, Vincenzo Fiore1
1Department of Engineering, University of Palermo, Viale delle Scienze, Edificio 6, 90128 Palermo, Italy.
Polymers
|January 25, 2025
概括
新型环保环氧粘合剂是使用聚胺 (PEI) 和聚ε-烯 (PCL) 开发的. 这些可持续的粘合剂为结构应用提供了更好的机械性能和可回收性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 粘合技术的技术 粘合技术
背景情况:
- 开发可持续和高性能粘合剂对于减少结构应用中的环境影响至关重要.
- 生物基和可回收的环氧树脂为传统的石油基粘合剂提供了一个有希望的替代品.
- 结合热塑性聚合物可以增强粘合性能,并使可回收性.
研究的目的:
- 通过将聚胺 (PEI) 和聚乙烯 (PCL) 纳入生物基环氧树脂来设计新型环氧粘合剂.
- 评估在不同温度下修改的粘合剂的机械,学,热和粘合性能.
- 评估开发的环氧粘合剂的可回收性和联合拆卸的潜力.
主要方法:
- 通过将PEI和PCL与生物基环氧树脂 (北极熊) 混合合成环氧粘合剂.
- 机械性能 (半静态和动态),风学,热稳定性和单关节的粘附性的表征.
- 在-55°C,23°C和80°C时测试粘附性能.
- 通过基于酸的工艺评估可回收性.
主要成果:
- 低PEI含量 (≤3重量%) 显著提高了机械性能和性,同时保持了可加工性.
- 超过3%重量的PEI含量会对机械阻力和可加工性产生负面影响.
- 添加PCL增加了粘度,但降低了机械性能,尽管它提供了环保性.
- 所有修改后的粘合剂在所有温度的膝盖剪切测试中都表现优于商业DP-460环氧粘合剂.
- 两种PEI和PCL修饰粘合剂都通过一种简单的基于酸的工艺证明了可回收性.
结论:
- 用PEI和PCL改性环氧粘合剂为结构粘合提供了一种高性能,环保的替代方案.
- 开发的粘合剂表现出出色的机械性能,热稳定性和粘合力,即使在极端温度下.
- 这些粘合剂的可回收性支持材料应用中的可持续实践和循环经济原则.
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