在NiFe2O4纳米粒子进行预度后,通过化物生成集成的微采样气液分离器-FAAS进行敏感的测定
Merve Fırat Ayyıldız1,2, Süleyman Bodur1,3,4, Sezgin Bakırdere5,6
1Faculty of Art and Science, Department of Chemistry, Yıldız Technical University, 34220, İstanbul, Türkiye.
Scientific reports
|January 25, 2025
概括
这项研究引入了一种新的方法,用于检测南极湖水中的,使用分散固相提取和火焰原子吸收光谱学. 开发的技术可以在环境样本中进行敏感的测定.
科学领域:
- 环境化学环境化学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 水生生态系统中的污染对环境构成风险.
- 准确地确定南极洲等偏远地区的含量对于环境监测至关重要.
- 开发敏感和高效的分析方法对于微量金属分析至关重要.
研究的目的:
- 开发和验证一种敏感的分析方法,用于在南极湖水中确定.
- 为了合成和描述新的微波辅助NiFe2O4纳米粒子用于固相提取.
- 为了优化集成的分散固体相提取和化物生成技术.
主要方法:
- 微波辅助合成NiFe2O4纳米粒子.
- 使用FT-IR,XRD和SEM进行纳米颗粒的表征.
- 分散固体相提取 (dSPE) 与化物生成 (HG) 和火焰原子吸收光谱 (FAAS) 相结合.
- 对dSPE和HG参数进行优化.
- 在南极洲马岛湖水样本中的分析.
主要成果:
- 成功合成和表征NiFe2O4纳米粒子.
- 优化的dSPE-HG-FAAS方法实现了2.16μg kg-1的检测极限 (LOD) 和7.19μg kg-1.1的量化极限 (LOQ).
- 恢复研究显示出不同的结果:102.0169.5%与外部校准和78.8142.9%与矩阵匹配校准.
结论:
- 开发的dSPE-HG-FAAS方法是南极湖水中敏感测定的一个有前途的技术.
- 校准策略的选择显著影响复杂矩阵中确定精度.
- 建议对矩阵效应和校准策略进行进一步调查,以进行可靠的分析.
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