过渡性分析,以实现多目标的操作性改进,以改善酸盐质量和从纳夫塔催化改造工艺中生产的生产
F Velázquez-Alonso1,2, C A González-Ramírez1, J R Villagómez-Ibarra1
1Área Académica de Química, Instituto de Ciencias Básicas e Ingeniería, Universidad Autónoma del Estado de Hidalgo. Ciudad del Conocimiento, Carretera Pachuca-Tulancingo Km. 4.5, C.P. 42184, Mineral de la Reforma, Hidalgo, Mexico.
Heliyon
|January 27, 2025
概括
这项研究使用过程模拟优化了催化纳改造 (CNR) 操作. 它找到了过渡模式,以提高重制质量和生产,这对于炼油厂过程至关重要.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 过程优化 过程优化
- 催化剂是一种催化剂.
背景情况:
- 通过催化纳改造 (CNR) 生产对于炼油厂的运营至关重要,它影响了过程反和下游水处理.
- 优化CNR对于最大限度地提高的产量和质量,同时改善酸盐的特性至关重要.
研究的目的:
- 通过过程模拟来确定CNR中最佳的过渡操作模式.
- 为了同时提高酸盐的质量 (研究八度数) 和的生产 (数量和纯度).
主要方法:
- 使用Aspen HYSYS®进行过程模拟,以建模催化纳改造单元.
- 运行条件的调查,包括/碳化合物的循环比 (2-6) 和温度 (450-525°C).
- 应用响应表面叠加和多目标分析来确定最佳参数.
主要成果:
- 确定了最佳的操作参数,导致研究八分数 (RON) 为90.72.
- 生产的的质量分数 (H2的%m) 为2.9,回收质量 (yH2) 为0.87,产生的质量 (yH2) 为0.9653.
- 模拟结果显示与实验试点工厂和工业数据有显著一致.
结论:
- 过程模拟有效地确定了改进CNR性能的过渡操作模式.
- 这项研究为提高生产的的数量和质量,以及改良质量的途径提供了途径.
- 经过验证的模拟模型为优化工业炼油厂流程提供了可靠的工具.
相关概念视频
Reduction of Alkenes: Catalytic Hydrogenation
11.8K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
11.8K
Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation
7.6K
Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
7.6K
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
4.3K
Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
4.3K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
3.2K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.2K
Catalysis
26.6K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
26.6K
Alcohols from Carbonyl Compounds: Reduction
10.2K
Reduction is a simple strategy to convert a carbonyl group to a hydroxyl group. The three major pathways to reduce carbonyls to alcohols are catalytic hydrogenation, hydride reduction, and borane reduction.
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...
Catalytic hydrogenation is similar to the reduction of an alkene or alkyne by adding H2 across the pi bond in the presence of transition metal catalysts like Raney Ni, Pd–C, Pt, or Ru. Aldehydes and ketones can be reduced by this method, often under mild to moderate heat (25–100°C) and...
10.2K


