通过催化氧化氧化氧化的奥斯瓦尔德工艺强化
Jithin Gopakumar1, Rune Myrstad2, Rebecka Bo Rresen Anda1
1Department of Chemical Engineering, Norwegian University of Science and Technology (NTNU), Sem Sælands vei 4, NO-7491 Trondheim, Norway.
ACS omega
|January 27, 2025
概括
在-支持上的催化剂通过有效氧化氧化物到二氧化来增强酸生产. 这种催化进步为加强已建立的奥斯瓦尔德过程提供了途径.
科学领域:
- 化学工程是化学工程的重要组成部分.
- 催化剂是一种催化剂.
- 工业化学 工业化学 工业化学
背景情况:
- 奥斯瓦尔德工艺是工业酸 (HNO3) 生产的基石,对于化肥至关重要.
- 尽管优化,但过程强化机会仍然存在,特别是在NO到NO2氧化过程中.
- 催化这一步骤可以显著提高整体效率.
研究的目的:
- 为了研究在- (γ-Al2O3) 上支持的的催化活性,用于NO到NO2的氧化.
- 评估这种催化剂在强化奥斯瓦尔德过程中的潜力.
- 在工业相关条件下评估催化剂性能.
主要方法:
- 洗涂层和γ-Al2O3在一个cordierit单体上.
- 用模拟的工业料气体在实验室规模的设置中测试催化剂.
- 在商业化肥厂的试点工厂评估催化剂性能.
主要成果:
- 在实验室测试中,Ru/γ-Al2O3催化剂在实验室测试中实现了72%的稳定转化.
- 试点工厂的测试表明,与单独的气相相比,转换率高出20%.
- 在试点试验中,催化剂在4天内保持了65小时的稳定转换.
结论:
- 在奥斯瓦尔德工艺条件下,g-Al2O3上的是氧化NO到NO2的有效催化剂.
- 这种催化方法代表了加强酸生产的重要一步.
- 这些发现支持Ru/γ-Al2O3的工业应用,用于增强化肥料制造.
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