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Updated: May 30, 2025

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

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在改性铜氧化物上协同增强反应剂和基的共吸附,用于高性能HMF氧化

Jiaran Li1, Rongxing Qiu1, Siwang Zhang1

  • 1Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005, P. R. China.

Advanced materials (Deerfield Beach, Fla.)
|January 28, 2025
PubMed
概括

这项研究开发了一种Pt/CuO催化剂,用于用电化学方法将生物质衍生的5-基甲基 (HMF) 转化为2,5-基酸 (FDCA). 催化剂表现出卓越的性能和稳定性,为关键聚合物单体提供可持续的途径.

关键词:
生物质提升生物质的升级.电催化剂是一种电催化剂.绿色化学 是一种绿色化学.不同质的催化剂.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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Alkenes can be dihydroxylated using potassium permanganate.  The method encompasses the reaction of an alkene with a cold, dilute solution of potassium permanganate under basic conditions to form a cis-diol along with a brown precipitate of manganese dioxide.
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Radical Oxidation of Allylic and Benzylic Alcohols

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