溶性共价有机框架作为高性能金属电池的高效性调节器
Shen Xu1,2, Tuoya Naren1,3, Yanwei Zhao1
1Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, 999077, P. R. China.
Angewandte Chemie (International ed. in English)
|January 28, 2025
概括
研究人员开发了可溶性共价有机框架 (COF) 来稳定金属电池 (LMB). 这些COF作为人工固体电解质介相作用,防止树的生长,增强电池的寿命和安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 金属电池 (LMB) 的能量密度高于离子电池,但会受到状物生长和不稳定的影响.
- 由于安全问题和短周期寿命,LMBs的商业化受到阻碍.
研究的目的:
- 为LMBs提出可溶性性共价有机框架 (COFs) 的设计策略.
- 通过防止树形成来解决LMB的不稳定性和安全问题.
主要方法:
- 通过结合聚乙烯糖醇侧链,合成了两种可溶性COF (CityU-28和CityU-29).
- 将合成的COF涂在阳极上,以形成人工固体电解质介相.
- 在对称和全电池电池中测试了修改后的阳极的性能.
主要成果:
- 可溶性COF促进了离子迁移,并作为有效的人工固体电解质介相.
- 城市U-29@Li对称电池证明了超过5000小时的稳定运行.
- 城市U-29@Li下载下载LiFePO4全电池在1500个循环后实现了78.9%的容量保留和99.9%的库伦比效率.
结论:
- 拟议的可溶性COF为稳定金属阳极提供了通用设计策略.
- 这种方法提高了金属电池的长期稳定性和安全性.
- 这些发现为COF在储能领域的先进应用铺平了道路.
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