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相关概念视频

Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

2.8K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
2.8K
Crystal Growth: Principles of Crystallization01:25

Crystal Growth: Principles of Crystallization

1.6K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
1.6K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.1K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.1K
Porosity in Cement Paste01:18

Porosity in Cement Paste

110
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
110
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

1.0K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
1.0K
Structures of Solids02:22

Structures of Solids

13.9K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
13.9K

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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

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部分结合的晶体:通往多孔性和多态性的途径

Carina Karner1, Emanuela Bianchi1,2

  • 1Institut für Theoretische Physik, TU Wien, Wiedner Hauptstraße 8-10, A-1040 Wien, Austria.

ACS nano
|January 28, 2025
PubMed
概括

具有故意移位的斑块的异型合体形成多孔晶体. 几何挫折和部分结合创造了奇拉单元,使新的晶体结构.

科学领域:

  • 体科学是关于体的科学.
  • 材料科学是一种材料科学.
  • 晶体学 晶体学是指结晶学.

背景情况:

  • 具有局部结合点 (补丁) 的异型合体自组织成有序的多孔单层.
  • 之前的假设要求不完全的粒子之间完全结合以形成晶体,而不完全的结合会导致混乱.

研究的目的:

  • 通过不利于完全结合来研究孔晶体单层的替代途径.
  • 探索几何挫折和部分结合在自组装中的作用.

主要方法:

  • 理论和实验研究的异性质合物.
  • 分析颗粒形状和补丁放置对自组装的影响.
  • 由此产生的结构和结合配置的表征.

主要成果:

  • 蓄意移动补丁会导致多孔晶体单层,这与之前的假设相反.
  • 几何挫折和部分粘合是这种新组装路径的关键驱动因素.
  • 悬挂的债券出现,形成有效的奇拉单元.

结论:

  • 孔隙的晶体单层可以形成,即使完全的粒子间结合是不利的.
  • 几何挫折和部分结合为设计有序体材料提供了一种新的机制.
关键词:
挫败感 挫败感 挫败感 挫败感斑点性的合物 斑点性的合物多形态主义的多态主义.自动组装的自动组装机形状 - 异构性异构性

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  • 奇拉单元的出现扩大了对自组装原理的理解.