通过使用无机凝固剂和有机聚合物进行序列凝固来去除物种的机制
Evelina Koltsova1, Roman Smotraiev2, Anastasiia Nehrii1
1Ukrainian State University of Science and Technologies, Department of Inorganic Substances Technology and Ecology, Science Avenue, 8, Dnipro 49005, Ukraine; Norwegian University of Life Sciences, Department of Building and Environmental Technology, P.O. Box 5003, 1430 Ås, Norway.
概括
这项研究将硫酸 (ALS) 与有机聚合物结合起来,以有效地去除并重复使用. 该方法显著减少了ALS的使用,同时提高了废水处理和污泥肥料价值.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 营养素管理 营养素管理
背景情况:
- 随着越来越多的温化,需要严格地从废水中去除.
- 全球酸盐短缺凸显了对高效酸盐再利用的需要.
- 传统的废水处理在完全去除方面面临着挑战.
研究的目的:
- 研究硫酸 (ALS) 和高分子量有机聚合物对去除效率的联合作用.
- 阐明增强颗粒,度,正酸盐 (OP) 和脂 (PL) 清除背后的机制.
- 评估这种综合处理对废水污泥肥料价值的影响.
主要方法:
- 使用硫酸 (ALS) 和各种有机聚合物进行凝血-花.
- 分析颗粒,度,正酸盐 (OP) 和脂 (PL) 的去除率.
- 测量泽塔电位,以了解电荷相互作用.
- 评估污泥的生物可用性和肥料潜力.
主要成果:
- 实现了95-99%的颗粒,度和酸盐的去除.
- 通过协同聚合物添加,ALS剂量减少了40%.
- 确定了聚合物电荷密度作为颗粒/度去除的关键,以及用于OP去除的泽塔电位转移.
- 通过吸附和电荷中和机制证明了增强的PL去除.
- 优化的两阶段剂量改善了PL去除,即使在低剂量的ALS.
结论:
- 结合ALS-聚合物系统为废水中的去除提供了高效和成本效益的解决方案.
- 了解OP和PL去除的机制可以提高治疗优化.
- 改善污泥中的回收增加了其作为肥料的价值,有助于营养循环.
相关概念视频
Coagulation
259
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
259
Factors Affecting Solubility
33.0K
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:
33.0K
The Phosphorus Cycle
36.4K
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
36.4K
Extraction: Advanced Methods
403
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
403
Colloidal precipitates
494
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
494
Precipitation and Co-precipitation
1.7K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.7K


