用于使用二 (二) 复合物的氧化还原流电池的机制引导的两电子能量存储
Md Musharraf Hossain1, Byron H Farnum1
1Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849, USA. farnum@auburn.edu.
概括
复合体储存多个电子,以提高氧化还原流电池 (RFB) 的能量密度. 控制电子传输路径优化了多电子存储,提高了电池性能和容量保留.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 无机化学 无机化学 有机化学
背景情况:
- 高能量密度对于推进氧化还原流电池 (RFB) 的发展至关重要.
- 每个分子储存多个电子为增加能量密度提供了一条途径.
- 复合体是RFB中多电子存储的有希望的候选者.
研究的目的:
- 为了研究双复合物的多电子存储能力.
- 了解协调环境如何影响电子转移通路.
- 优化复合物以提高RFB中作为解质的性能.
主要方法:
- 合成和表征二 (二二) 复合体与不同的配体.
- 电化学研究 (循环电压测量) 来分析氧化还原行为和电子转移.
- 连续充放电循环,以评估电池性能和容量保留.
主要成果:
- 二 (二) 复合体表现出连续的1e-或协同的2e-氧化还原波.
- 连接体和单连接体的协调 (例如,Cl-) 控制电子转移通路.
- 化物协调有利于2e-路径,导致更多的负潜力和更好的容量保留.
结论:
- 对电子转移通路的机械控制使复合体中高效的多电子存储成为可能.
- 优化的二 (二) 复合物显示出作为RFBs的高性能解质的巨大潜力.
- 了解2e-redox循环是开发下一代储能解决方案的关键.
更多相关视频
09:02Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
Published on: April 27, 2018
7.7K
07:55Elemental-sensitive Detection of the Chemistry in Batteries through Soft X-ray Absorption Spectroscopy and Resonant Inelastic X-ray Scattering
Published on: April 17, 2018
12.6K
相关概念视频
Batteries and Fuel Cells
26.9K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
26.9K
Voltaic/Galvanic Cells
56.6K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.6K
Oxidation and Reduction of Organic Molecules
6.1K
Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
The removal of an electron from a molecule, results in a...
6.1K
Redox Equilibria: Overview
513
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
513
Role of Reduced Coenzymes NADH and FADH₂
11.1K
The energy released from the breakdown of the chemical bonds within nutrients can be stored either through the reduction of electron carriers or in the bonds of adenosine triphosphate (ATP). In living systems, a small class of compounds functions as mobile electron carriers, molecules that bind to and shuttle high-energy electrons between compounds in pathways. The principal electron carriers that will be considered originate from the B vitamin group and are derivatives of nucleotides; they are...
11.1K
Electron Carriers
84.0K
Electron carriers can be thought of as electron shuttles. These compounds can easily accept electrons (i.e., be reduced) or lose them (i.e., be oxidized). They play an essential role in energy production because cellular respiration is contingent on the flow of electrons.
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
Over the many stages of cellular respiration, glucose breaks down into carbon dioxide and water. Electron carriers pick up electrons lost by glucose in these reactions, temporarily storing and releasing them into the electron...
84.0K
