玻璃状水凝的压力放松和爬行反应具有密集的物理关联
Hao Nan Qiu1, Ji Lin2,3, Li Xin Hou1
1Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China.
ACS applied materials & interfaces
|January 31, 2025
概括
玻璃状水凝表现出独特的粘性塑性行为,由于破坏了键. 它们在应力下快速激活部分,为设计更坚固的材料提供了洞察力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 类风病学 类风病学 类风病学
背景情况:
- 由于密集的物理关联,玻璃式水凝具有很高的刚性和性.
- 了解它们的机械行为对于材料设计至关重要.
研究的目的:
- 研究聚甲胺-协同甲酸) 玻璃水凝的粘性塑料行为.
- 分析它们机械反应的潜在机制.
主要方法:
- 使用了压力放松和爬行测量.
- 建立了一个基于剪切转换区理论的微机械模型.
主要成果:
- 玻璃状水凝比无形聚合物具有较小的特征放松时间.
- 键强度分布影响了放松时间.
- 产前和产后制度表现出不同的放松行为.
- 爬行测试显示了最初的加速,然后是延展率的减速.
结论:
- 玻璃式水凝不处于热力学平衡状态,显示出快速的断片激活.
- 微机械模型通过包括键密度来捕捉复杂的机械反应.
- 这些发现有助于我们更好地理解玻璃状材料的动力学和结构稳定性,以适用于固的水凝应用.
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