:绿色,耐火复合材料行业的开创性自然资源
Hassan Soltan Hassan1,2, Ahmed S Elshimy3, Isabel Israde-Alcantara4
1Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito exterior s/n, Ciudad Universitaria, Del. Coyoacán, Ciudad de México 04510, Mexico.
ACS omega
|February 3, 2025
概括
研究人员开发了一种新型的环保,耐火复合材料,使用活性氧化 (AAOB). 在工业应用中,AAOB表现出优越的机械强度和耐热性,与基于金属的地质聚合物 (MKBG) 相比.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 工程材料 工程材料
背景情况:
- 开发可持续和高性能材料对于苛刻的工业应用至关重要.
- 传统的耐火材料往往会对环境产生不利影响.
- 需要具有增强机械和热性能的环保复合材料.
研究的目的:
- 开发一种创新的,环保的,耐火复合材料,采用更清洁的生产方法.
- 为了比较活性化氧化 (AAOB) 与基于甲的地质聚合物 (MKBG) 的性能.
- 评估开发材料的机械强度,耐火性和热性能.
主要方法:
- 新型的氧化 (OB) 和甲 (MK) 用NaOH在不同比例 (8-12重%) 的活性化.
- 材料在80°C的温度下固化,形成AAOB和MKBG.
- 综合性表征包括压力强度测试,导热度测量,XRD,XRF,TGA,FTIR,SEM和EDX分析.
主要成果:
- 与MKBG (高达25.66MPa) 相比,AAOB的压力强度明显更高 (高达101MPa).
- 在恶劣条件下,AAOB表现出优越的耐火性和机械强度.
- 在1000°C,AAOB比MKBG (33%的多孔度,0.901W/mK) 呈现出更高的孔度 (80%) 和更低的导热率 (0.193W/mK).
结论:
- 活性 (AAOB) 是一个有前途的绿色复合材料,具有卓越的耐火性和机械性能.
- 在关键性能指标上,AAOB优于MKBG,因此适用于超高温的工业和建筑应用.
- 开发的AAOB代表了可持续耐火复合材料的重大进步.
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