通过采用固有的微孔离子体来降低燃料电池催化剂层内的氧气运输阻力
Wei Yuan1, Shimei Liang1, Xiufang Zheng1
1State Key Laboratory of Advanced Chemical Power Sources, School of Chemistry & Chemical Engineering, Chongqing University, Chongqing, 400044, China. zdwei@cqu.edu.cn.
概括
一种具有内在微孔性的新型硫酸离子体通过改善三相边界来提高燃料电池性能. 这种催化剂结合剂显著降低了氧气运输阻力,并提高了低燃料电池的峰值功率密度.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 质子交换膜燃料电池 (PEMFCs) 对清洁能源至关重要.
- 为了降低成本,希望使用低负载,但挑战性能.
- 需要有效的催化剂结合剂来优化反应动力学和质量传输.
研究的目的:
- 设计和合成具有内在微孔性的硫酸离子体.
- 为了利用这种离子体作为低Pt载荷燃料电池中的催化剂结合剂.
- 评估其对三相边界和燃料电池整体性能的影响.
主要方法:
- 一种具有内在微性的硫酸离子体的合成.
- 制造具有新型离子体结合剂的催化剂层.
- 低Pt载荷燃料电池的电化学表征,包括阻抗光谱和极化曲线.
主要成果:
- 设计的离子体结合剂有效地形成了有利的三相边界.
- 观察到局部氧气运输阻力显著减少57%.
- 在峰值功率密度上实现了显著的47%的增长,达到1233mW cm-2.
结论:
- 本质的微孔硫酸离子体是低Pt载荷燃料电池的有前途的催化剂结合剂.
- 改进的氧气传输和三相边界是提高功率密度的关键.
- 这种材料为经济高效,高性能燃料电池开发提供了可行的策略.
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