在粘性弹性接口上电控扩散表面活性剂装载滴滴
Sumit Kumar1,2, Purbarun Dhar1, Suman Chakraborty1
1Department of Mechanical Engineering, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India.
Langmuir : the ACS journal of surfaces and colloids
|February 5, 2025
概括
表面活性剂通过动态降低界面张力,克服粘性消散,增强滴滴在软表面的传播. 这一发现解释了接触角度的依赖性,并使生物模拟材料的控制传播成为可能.
科学领域:
- 软物质物理学 软物质物理学
- 表面科学是一门科学.
- 生物材料是一种生物材料.
背景情况:
- 滴滴在软表面上的传播涉及接触线和基板变形之间的复杂相互作用.
- 软材料的粘弹性特性导致能量消散,通常会阻碍传播.
研究的目的:
- 研究表面活性剂分子对电气诱导的动态滴滴在软表面传播的影响.
- 阐明在表面活性剂的存在下观察到的增强传播速度背后的机制.
主要方法:
- 电气诱导的动态扩散的特征.
- 由于表面活性剂分布而导致的界面能量调制的分析.
- 缩放理论应用于接触角度动态.
主要成果:
- 表面活性剂的存在意外地增加了滴滴的传播速度.
- 固体-液体界面张力的动态降低克服了基板粘度.
- 扩散动态显示出对初始接触角度的敏感依赖.
结论:
- 用表面活性剂重新分配表面能量是增强动态传播的关键.
- 这些发现为控制软,仿生界面上的滴滴行为提供了科学基础.
- 该研究合理化了以前无法解释的扩散对初始接触角度的依赖.
相关概念视频
Surface Tension, Capillary Action, and Viscosity
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
Surface Tension
Surface tension is defined as the force per unit length (γ) acting along the surface of a liquid. It arises due to strong intermolecular forces of attraction. A molecule located inside the bulk of the liquid is surrounded by other molecules and experiences equal forces in all directions. However, a molecule at the surface experiences unbalanced forces because there are more neighboring molecules below than above. This creates a net inward force that pulls surface molecules toward the interior,...
Surface Active Agents
Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...
Surface Tension of Fluid
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies with...
Surface tension varies with...


