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操纵聚合动力学,实现高效的全打印有机太阳能电池.

Junzhen Ren1,2, Jianqiu Wang1, Jiawei Qiao3

  • 1State Key Laboratory of Polymer Physics and Chemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.

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概括

研究人员开发了一种新的非富勒烯受体,BTP-Cy,具有环基侧链,以改善有机太阳能电池 (OSC) 打印. 这种分子设计增强了薄膜的形成,提高了印刷OSC的功率转换效率 (PCE).

关键词:
刀片上的涂层是叶片的涂层.这是一种循环基基.分子设计分子设计.形态控制 控制 形态控制有机太阳能电池是有机太阳能电池.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 有机电子 有机电子
  • 太阳能光伏发电是如何实现的

背景情况:

  • 全打印的有机太阳能电池 (OSC) 显示较低的功率转换效率 (PCE) 与旋转涂层设备相比.
  • 大量异质连接层的形态变异是印刷OSC的一个关键限制.

研究的目的:

  • 在非富勒接受器 (BTP-Cy) 中引入环基侧链,以控制印刷过程中的分子聚合和薄膜形成.
  • 通过分子设计提高全打印OSC的性能.

主要方法:

  • 合成一种新型非富勒烯受体BTP-Cy,其中包含环基侧链.
  • 使用新材料的旋转涂层和叶片涂层技术制造OSC.
  • 分子聚合的特征,膜形态和光伏性能.

主要成果:

  • BTP-Cy 显示了增强的分子间 π-π 堆叠,最佳的溶液聚合和有利的相位分离.
  • 基于 PB3:FTCC-Br:BTP-Cy 的 OSC 实现了 20.2% 的 PCE (螺纹涂层) 和 19.5% 的 PCE (叶片涂层).
  • 一个23.6厘米2模块的效率达到了16.7%.

结论:

  • 环基侧链有效调节印刷OSC中的薄膜形成动力学.
  • 非富勒受体的分子设计是一种可行的策略,可以提高全打印OSC的效率.
  • 这项工作为开发高性能印刷有机太阳能电池提供了一种新方法.