通过构建强有力的共价键,限制P2类层氧化物中层间的滑动
Xinyin Cai1, Zulipiya Shadike1, Nan Wang2
1Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Journal of the American Chemical Society
|February 5, 2025
概括
在P2型层氧化物中引入,可以实现Z相过渡,增强离子电池阴极. 这种策略提高了结构稳定性和离子扩散,提高了能量密度和性能.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 在P2型层氧化物中,离子电池具有很高的能量密度.
- 然而,LOR可能会导致结构扭曲和不可逆转的相位过渡,降低性能.
研究的目的:
- 在P2型层氧化物中用稳定的Z相取代有害的OP4相.
- 通过引入 (Sb) 来提高离子电池阴极的电化学性能.
主要方法:
- 在P2型氧化物中用Sb取代过渡金属 (TM) 层.
- 阶段过渡和结构稳定性的分析.
- 半细胞和全细胞的电化学测试.
主要成果:
- Sb的引入促进了Z相过渡,抑制了OP4相形成.
- Z阶段过渡降低了结构应变并降低了Na+扩散障碍.
- 替代氧化物具有出色的动力学,速度能力 (79 mAh g-1在1 A g-1),以及高能量密度 (487 Wh kg-1).
结论:
- 通过Sb替换用Z相取代OP4是稳定的高能离子电池阴极的可行策略.
- 这种方法减轻了LOR引起的降解,为实际应用铺平了道路.
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