无压力双向形状记忆聚合物,具有基于聚四甲乙烯基醇和聚ε-烯酸的双晶相
Bingyan Zhang1, Jie Jiang1,2, Jinjin Li1
1State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China.
Macromolecular rapid communications
|February 6, 2025
概括
研究人员开发了双晶相交联聚合物网络,以精确控制双向形状记忆聚合物 (2W-SMP). 这些智能材料在没有外力的情况下表现出可逆变形,显示出软机器人的潜力.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 双向形状记忆聚合物 (2W-SMPs) 是一种智能材料,能够在应对刺激时自发,可逆变形.
- 对2W-SMP行为的精确控制和理解它们的结构-属性关系对于高级应用程序至关重要.
研究的目的:
- 制造双晶相交联聚合物网络,用于控制的双向形状记忆效果.
- 研究这些新的聚合物网络中规范双向形状记忆行为的结构-属性关系.
主要方法:
- 制造双晶相交联聚合物网络,使用聚四甲乙烯乙醇 (PTMEG) 和聚ε-烯酸 (PCL) 通过乙烯点击反应.
- 调整网络组合以实现独立的融温度,并通过相间温度差异实现双向形状记忆.
- 调查网络组成,前拉力应变和启动温度对形状记忆特性的影响.
主要成果:
- 成功制造出具有两种不同的化温度的聚合物网,从而实现温度控制的双向形状记忆.
- PTMEG8-PCL2组合表现出最佳性能,执行应变率为24.25%,可逆应变率高达10.35%在45°C和15%的预拉伸.
- 在双晶相聚合物的双向形状记忆机制的阐释.
结论:
- 该研究成功设计和制造了具有控制的双向形状记忆特性的双晶相聚合物网络.
- 这些发现为设计半晶体网络提供了可调节的双向形状记忆效果的途径.
- 开发的2W-SMP显示了软机器人应用的巨大潜力.
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