在页岩气层中存储CO2和H2的微尺度运输和储存
1University of Wyoming, Department of Chemical and Biomedical Engineering, Laramie, Wyoming 82071, USA.
Physical review. E
|February 7, 2025
概括
这项研究模拟了二氧化碳 (CO2) 和 (H2) 在页岩中进行存储的微观运输. 不同的分子特性影响了CO_{2}和H_{2}如何在纳米孔中取代甲 (CH_{4}).
科学领域:
- 地质科学 地质科学
- 化学工程是化学工程的重要组成部分.
- 计算物理 计算物理
背景情况:
- 页岩气层是地下储存二氧化碳 (CO2) 和 (H2) 等气体的关键.
- 了解微观运输行为对于高效和安全的存储操作至关重要.
- 纳米孔介质中的二元混合动力学对建模具有复杂的挑战.
研究的目的:
- 模拟和分析二元气体混合物 (CH_{4}-CO_{2}和CH_{4}-H_{2}) 在页岩气层中的微观运输行为.
- 研究压力,构成和孔径几何学对运输特性的影响.
- 为了阐明CO_{2}和H_{2}相对于CH_{4}在纳米封闭空间中的移位机制.
主要方法:
- 实现一个多重放松时间格子博尔兹曼 (LB) 模型用于微尺度模拟.
- 使用混合反弹和镜面反射边界方案,用于流体壁相互作用和滑动.
- 采用规范化算法来准确模拟复杂几何形状,并通过标准问题和纳米孔流验证.
主要成果:
- 在各种条件下对流体速度,质量流量,表面透率,Péclet数和压力下降进行全面检查.
- 观察到CO_{2}和H_{2}在取代CH_{4}时有不同的排位机制,归因于不同的分子性质.
- 量化了压力和组成对二元混合物在切片和不规则纳米孔中的运输动态的影响.
结论:
- 该研究提供了关于CO2和H2的微观运输的关键见解,这与它们在页岩气储库中的地下储存有关.
- 格子博尔茨曼模型有效地捕获了纳米级的复杂流体动力学和位移行为.
- 了解分子性质影响对于预测储存效率和水库行为至关重要.
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