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可伸缩弹性体的裂传播中不连续的动态转变
1University of Akron, School of Polymer Science and Polymer Engineering, Akron, Ohio 44325, USA.
Physical review. E
|February 7, 2025
概括
高延展性弹性体表现出独特的断裂过渡,其中裂纹速度随着拉伸而突然变化. 这种现象与裂传播期间的纽带解离和网络演变有关.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 断裂力学 断裂力学 断裂力学
背景情况:
- 高延展性弹性体表现出不连续的断裂过渡.
- 裂纹传播速度在特定的拉伸范围内变为双重值.
- 这种过渡可以通过连续或步骤拉伸来触发.
研究的目的:
- 调查弹性体中不连续断裂过渡的潜在机制.
- 了解网络演变,链张力和裂传播速度之间的关系.
- 阐明温度和拉伸大小对断裂行为的作用.
主要方法:
- 在不同的拉伸条件下分析裂传播动态.
- 在骨折过程中对弹性体网络行为的研究.
- 断裂速度与温度和施加的应变的相关性.
主要成果:
- 裂传播速度随着温度升高而急剧增加,这表明脊柱键解离.
- 断裂过渡取决于网络重新分配链张力的能力.
- 在临界拉伸以上,只有快速的裂生长发生;在最小拉伸以下,只观察到缓慢的裂生长.
结论:
- 弹性体中不连续的断裂过渡是由网络骨干键的解离驱动的.
- 网络演变和链张力再分配是管理过渡的关键因素.
- 伸展大小在确定断裂模式 (缓慢与快速裂纹生长) 中起着至关重要的作用.
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