煤气化煤炭的共同燃烧特点 飞灰和煤炭由循环流化床预热
Jicheng Hui1, Jiangong Lin2, Shujun Zhu3
1North China Electric Power University, Beijing 102206 China; State Key Laboratory of Coal Conversion, Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190 China.
Waste management (New York, N.Y.)
|February 9, 2025
概括
通过预热联合燃烧煤气化飞灰 (CGFA) 和煤炭 (CG),提高了燃烧效率并减少了废物. 通过25%的煤混合物获得最佳效果,增强了煤炭的性能并最大限度地减少了有害排放.
科学领域:
- 环境科学 环境科学
- 化学工程是化学工程的重要组成部分.
- 材料科学 材料科学 材料科学
背景情况:
- 煤气化飞灰 (CGFA) 和煤炭 (CG) 的不当处置带来了重大的环境风险.
- 预热燃烧是一种有效的固体燃料利用方法.
- CGFA和CG具有互补的特性,适合协同燃烧.
研究的目的:
- 调查CGFA和CG混合物的预热修饰和共燃特性.
- 为了确定最佳的混合比,提高燃烧和减少排放.
- 分析活性炭的物理化学结构演变.
主要方法:
- 采用预热技术,在各种混合比率下共同燃烧CGFA和CG.
- 使用颗粒大小分析仪,扫描电子显微镜,N2吸附-溶解和拉曼光谱分析活性炭的分析.
- 燃烧效率和排放 (NO,N2O) 的评估.
主要成果:
- 在25%-50%的CG混合比率下实现稳定的预热燃烧.
- 添加CGFA改善了混合燃料的表面结构.
- 煤炭的特定表面积和化学反应性显著增加,最高活性为25%CG.
- 在CGFA固定碳和CG挥发物之间观察到协同效应.
- 在25%-50%的CG混合物中,燃烧效率得到了提高.
- 25%CG的最佳混合比率导致NO和N2O排放分别为121 mg/cm3和14 mg/cm3.
结论:
- 同时燃烧CGFA和CG与预热修改是一种可行的废物利用策略.
- 混合率为25%的CG,在燃烧活性,燃烧效率和排放控制方面提供最佳性能.
- 该研究表明,在改善燃烧过程的同时,在固体废物管理方面采取了协同方法.
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