Search

Search

这页已由机器翻译。其他页面可能仍然显示为英文。 View in English

首页
...
研究领域工程学化学工程能源和燃烧中的化学和热过程
在Crystallo中,Wolff对金属化的重新排列:单基碳素Wolff中间体的结构确认

在Crystallo中,Wolff对金属化的重新排列:单基碳素Wolff中间体的结构确认

Ze-Jie Lv ¹, Arnd Fitterer ², Regine Herbst-Irmer ¹, Serhiy Demeshko ¹, Hendrik Verplancke ², Max C Holthausen ², Sven Schneider ¹

Ze-Jie Lv ¹, Arnd Fitterer ², Regine Herbst-Irmer ¹

¹Institut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.
²Institut für Anorganische und Analytische Chemie, Goethe-Universität, Max-von-Laue-Straße 7, 60438 Frankfurt am Main, Germany.

⁰Institut für Anorganische Chemie and International Center for Advanced Studies of Energy Conversion (ICASEC), University of Göttingen, Tammannstraße 4, 37077 Göttingen, Germany.

Journal of the American Chemical Society +

|

2025年二月11日

相关实验视频

These videos have been matched automatically. Contact us if they are not relevant.

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange

Published on: June 23, 2023

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Published on: January 17, 2020

See all related videos

在PubMed上查看摘要

概括

此摘要是机器生成的。

研究人员在结构上描述了一种短暂的沃尔夫金属碳化合物中间体,这是沃尔夫重组反应中的关键物种. 这一突破为通过二碳化合物合成的基因机制提供了关键的见解.

科学领域

有机金属化学
反应机制
合成有机化学

背景情况

沃尔夫重组 (WR) 是从二基和基合成的重要反应.
在WR中提出过渡性碳烯中间体,但缺乏结构性表征.

研究的目的

从结构上描述一个沃尔夫金属碳酸中间体.
阐明沃尔夫重组中的反应性中间体的性质.

主要方法

一个diazoester配体的光启动碎片.
冷溶液和晶体矩阵的分离技术.
光谱 (NMR,IR,UV-Vis),磁性,晶体和计算分析.

主要成果

作为一种短暂的中间体的沃尔夫金属碳素 (PtII-C-C(O) -OEt) 的分离和表征.
确认金属碳的单体基态.
在中心和替代剂之间确定稳定 π 相互作用.

结论

这项研究提供了沃尔夫金属碳酸中间体的第一个结构特征.
这些发现证实了沃尔夫重组的建议机制.
这项研究补充了对有机沃尔夫重组的现有研究,通过表征金属结合的类似物.

相关实验视频

这些视频已自动匹配 Contact us 如果它们不相关

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange

Synthesis of Triazole and Tetrazole-Functionalized Zr-Based Metal-Organic Frameworks Through Post-Synthetic Ligand Exchange

Published on: June 23, 2023

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks (MOFs)

Published on: January 17, 2020

See all related videos

Share

X
Facebook
LinkedIn
YouTube

ABOUT JoVE

Overview
Leadership
Blog
JoVE Help Center

AUTHORS

Publishing Process
Editorial Board
Scope & Policies
Peer Review
FAQ
Submit

LIBRARIANS

Testimonials
Subscriptions
Access
Resources
Library Advisory Board
FAQ

RESEARCH

JoVE Journal
Methods Collections
JoVE Encyclopedia of Experiments
Archive

EDUCATION

JoVE Core
JoVE Business
JoVE Science Education
JoVE Lab Manual
Faculty Resource Center
Faculty Site

Terms & Conditions of Use
Privacy Policy
Policies